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Crystal structure of bis(η(5)-cyclopentadienyl)(2,3-diethylbutane-1,4-diyl)hafnium(IV)
The title compound, [Hf(C(5)H(5))(2)(C(8)H(16))], proves a structural motif of hafnacyclopentane besides the coordination of two cyclopentadienyl ligands in an η(5)-fashion. The hafnacyclopentane ring has a twist conformation and is substituted by two ethyl groups in the β,β′-positions, which...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331853/ https://www.ncbi.nlm.nih.gov/pubmed/25705475 http://dx.doi.org/10.1107/S2056989014026929 |
Sumario: | The title compound, [Hf(C(5)H(5))(2)(C(8)H(16))], proves a structural motif of hafnacyclopentane besides the coordination of two cyclopentadienyl ligands in an η(5)-fashion. The hafnacyclopentane ring has a twist conformation and is substituted by two ethyl groups in the β,β′-positions, which are trans orientated to each other. One cyclopentadienyl ring and one ethyl group are each disordered over two positions with site-occupancy ratios of 0.679 (15):0.321 (15) and 0.702 (18):0.298 (18), respectively. |
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