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Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate
[Bis(trimethylsilyl)amino](tert-butylimino)thiophosphorane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the molecule, the P atom possesses a distorted tetrahedral environment in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/ https://www.ncbi.nlm.nih.gov/pubmed/25705495 http://dx.doi.org/10.1107/S205698901402622X |
Sumario: | [Bis(trimethylsilyl)amino](tert-butylimino)thiophosphorane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the molecule, the P atom possesses a distorted tetrahedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the molecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enantiomers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds. |
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