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Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate

[Bis(tri­methyl­sil­yl)amino](tert-butyl­imino)­thio­phospho­rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the mol­ecule, the P atom possesses a distorted tetra­hedral environment in...

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Detalles Bibliográficos
Autores principales: Kovalenko, Oleksandr O., Kinzhybalo, Vasyl, Brusylovets, Oleksii A., Lis, Tadeusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/
https://www.ncbi.nlm.nih.gov/pubmed/25705495
http://dx.doi.org/10.1107/S205698901402622X
Descripción
Sumario:[Bis(tri­methyl­sil­yl)amino](tert-butyl­imino)­thio­phospho­rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the mol­ecule, the P atom possesses a distorted tetra­hedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the mol­ecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enanti­omers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds.