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Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate
[Bis(trimethylsilyl)amino](tert-butylimino)thiophosphorane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the molecule, the P atom possesses a distorted tetrahedral environment in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/ https://www.ncbi.nlm.nih.gov/pubmed/25705495 http://dx.doi.org/10.1107/S205698901402622X |
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author | Kovalenko, Oleksandr O. Kinzhybalo, Vasyl Brusylovets, Oleksii A. Lis, Tadeusz |
author_facet | Kovalenko, Oleksandr O. Kinzhybalo, Vasyl Brusylovets, Oleksii A. Lis, Tadeusz |
author_sort | Kovalenko, Oleksandr O. |
collection | PubMed |
description | [Bis(trimethylsilyl)amino](tert-butylimino)thiophosphorane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the molecule, the P atom possesses a distorted tetrahedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the molecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enantiomers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds. |
format | Online Article Text |
id | pubmed-4331855 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43318552015-02-20 Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate Kovalenko, Oleksandr O. Kinzhybalo, Vasyl Brusylovets, Oleksii A. Lis, Tadeusz Acta Crystallogr E Crystallogr Commun Data Reports [Bis(trimethylsilyl)amino](tert-butylimino)thiophosphorane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the molecule, the P atom possesses a distorted tetrahedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the molecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enantiomers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331855/ /pubmed/25705495 http://dx.doi.org/10.1107/S205698901402622X Text en © Kovalenko et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Kovalenko, Oleksandr O. Kinzhybalo, Vasyl Brusylovets, Oleksii A. Lis, Tadeusz Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title | Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title_full | Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title_fullStr | Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title_full_unstemmed | Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title_short | Crystal structure of O-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
title_sort | crystal structure of o-isopropyl [bis(trimethylsilyl)amino](tert-butylamino)phosphinothioate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/ https://www.ncbi.nlm.nih.gov/pubmed/25705495 http://dx.doi.org/10.1107/S205698901402622X |
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