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Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate

[Bis(tri­methyl­sil­yl)amino](tert-butyl­imino)­thio­phospho­rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the mol­ecule, the P atom possesses a distorted tetra­hedral environment in...

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Autores principales: Kovalenko, Oleksandr O., Kinzhybalo, Vasyl, Brusylovets, Oleksii A., Lis, Tadeusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/
https://www.ncbi.nlm.nih.gov/pubmed/25705495
http://dx.doi.org/10.1107/S205698901402622X
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author Kovalenko, Oleksandr O.
Kinzhybalo, Vasyl
Brusylovets, Oleksii A.
Lis, Tadeusz
author_facet Kovalenko, Oleksandr O.
Kinzhybalo, Vasyl
Brusylovets, Oleksii A.
Lis, Tadeusz
author_sort Kovalenko, Oleksandr O.
collection PubMed
description [Bis(tri­methyl­sil­yl)amino](tert-butyl­imino)­thio­phospho­rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the mol­ecule, the P atom possesses a distorted tetra­hedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the mol­ecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enanti­omers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds.
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spelling pubmed-43318552015-02-20 Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate Kovalenko, Oleksandr O. Kinzhybalo, Vasyl Brusylovets, Oleksii A. Lis, Tadeusz Acta Crystallogr E Crystallogr Commun Data Reports [Bis(tri­methyl­sil­yl)amino](tert-butyl­imino)­thio­phospho­rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i)PrO–H bond across the P=N bond, resulting in the title compound, C(13)H(35)N(2)OPSSi(2). In the mol­ecule, the P atom possesses a distorted tetra­hedral environment involving two N atoms from (Me(3)Si)(2)N– and (t)BuNH– groups, one O atom from an (i)PrO group and one S atom, therefore the mol­ecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enanti­omers form a centrosymmetric dimer via a pair of N—H⋯S hydrogen bonds. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331855/ /pubmed/25705495 http://dx.doi.org/10.1107/S205698901402622X Text en © Kovalenko et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kovalenko, Oleksandr O.
Kinzhybalo, Vasyl
Brusylovets, Oleksii A.
Lis, Tadeusz
Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title_full Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title_fullStr Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title_full_unstemmed Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title_short Crystal structure of O-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
title_sort crystal structure of o-isopropyl [bis­(tri­methyl­sil­yl)amino](tert-butyl­amino)­phosphino­thio­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331855/
https://www.ncbi.nlm.nih.gov/pubmed/25705495
http://dx.doi.org/10.1107/S205698901402622X
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