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Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol
The title compound, C(19)H(16)N(2)O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H⋯N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, res...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331856/ https://www.ncbi.nlm.nih.gov/pubmed/25705442 http://dx.doi.org/10.1107/S2056989014026309 |
Sumario: | The title compound, C(19)H(16)N(2)O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H⋯N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, respectively. The conformation of the two molecules differs essentially in the orientation of the terminal aminophenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in molecule A and 54.61 (14)° in molecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in molecules A and B, respectively. In the crystal, molecules are connected by N—H⋯O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H⋯π interactions involving neighbouring A molecules, forming slabs lying parallel to (100). |
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