Cargando…
Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol
The title compound, C(19)H(16)N(2)O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H⋯N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, res...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331856/ https://www.ncbi.nlm.nih.gov/pubmed/25705442 http://dx.doi.org/10.1107/S2056989014026309 |
_version_ | 1782357794834350080 |
---|---|
author | Faizi, Md. Serajul Haque Iskenderov, Turganbay S. Sharkina, Natalia O. |
author_facet | Faizi, Md. Serajul Haque Iskenderov, Turganbay S. Sharkina, Natalia O. |
author_sort | Faizi, Md. Serajul Haque |
collection | PubMed |
description | The title compound, C(19)H(16)N(2)O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H⋯N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, respectively. The conformation of the two molecules differs essentially in the orientation of the terminal aminophenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in molecule A and 54.61 (14)° in molecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in molecules A and B, respectively. In the crystal, molecules are connected by N—H⋯O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H⋯π interactions involving neighbouring A molecules, forming slabs lying parallel to (100). |
format | Online Article Text |
id | pubmed-4331856 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43318562015-02-20 Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol Faizi, Md. Serajul Haque Iskenderov, Turganbay S. Sharkina, Natalia O. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(16)N(2)O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H⋯N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, respectively. The conformation of the two molecules differs essentially in the orientation of the terminal aminophenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in molecule A and 54.61 (14)° in molecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in molecules A and B, respectively. In the crystal, molecules are connected by N—H⋯O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H⋯π interactions involving neighbouring A molecules, forming slabs lying parallel to (100). International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331856/ /pubmed/25705442 http://dx.doi.org/10.1107/S2056989014026309 Text en © Faizi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Faizi, Md. Serajul Haque Iskenderov, Turganbay S. Sharkina, Natalia O. Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title | Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title_full | Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title_fullStr | Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title_full_unstemmed | Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title_short | Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol |
title_sort | crystal structure of (e)-2-{[(4-anilinophenyl)imino]methyl}phenol |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331856/ https://www.ncbi.nlm.nih.gov/pubmed/25705442 http://dx.doi.org/10.1107/S2056989014026309 |
work_keys_str_mv | AT faizimdserajulhaque crystalstructureofe24anilinophenyliminomethylphenol AT iskenderovturganbays crystalstructureofe24anilinophenyliminomethylphenol AT sharkinanataliao crystalstructureofe24anilinophenyliminomethylphenol |