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Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol

The title compound, C(19)H(16)N(2)O, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. There is an intra­molecular O—H⋯N hydrogen bond in each mol­ecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in mol­ecules A and B, res...

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Autores principales: Faizi, Md. Serajul Haque, Iskenderov, Turganbay S., Sharkina, Natalia O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331856/
https://www.ncbi.nlm.nih.gov/pubmed/25705442
http://dx.doi.org/10.1107/S2056989014026309
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author Faizi, Md. Serajul Haque
Iskenderov, Turganbay S.
Sharkina, Natalia O.
author_facet Faizi, Md. Serajul Haque
Iskenderov, Turganbay S.
Sharkina, Natalia O.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The title compound, C(19)H(16)N(2)O, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. There is an intra­molecular O—H⋯N hydrogen bond in each mol­ecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in mol­ecules A and B, respectively. The conformation of the two mol­ecules differs essentially in the orientation of the terminal amino­phenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in mol­ecule A and 54.61 (14)° in mol­ecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in mol­ecules A and B, respectively. In the crystal, mol­ecules are connected by N—H⋯O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H⋯π inter­actions involving neighbouring A mol­ecules, forming slabs lying parallel to (100).
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spelling pubmed-43318562015-02-20 Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol Faizi, Md. Serajul Haque Iskenderov, Turganbay S. Sharkina, Natalia O. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(16)N(2)O, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. There is an intra­molecular O—H⋯N hydrogen bond in each mol­ecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in mol­ecules A and B, respectively. The conformation of the two mol­ecules differs essentially in the orientation of the terminal amino­phenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in mol­ecule A and 54.61 (14)° in mol­ecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in mol­ecules A and B, respectively. In the crystal, mol­ecules are connected by N—H⋯O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H⋯π inter­actions involving neighbouring A mol­ecules, forming slabs lying parallel to (100). International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331856/ /pubmed/25705442 http://dx.doi.org/10.1107/S2056989014026309 Text en © Faizi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Iskenderov, Turganbay S.
Sharkina, Natalia O.
Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title_full Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title_fullStr Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title_full_unstemmed Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title_short Crystal structure of (E)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
title_sort crystal structure of (e)-2-{[(4-anilinophen­yl)imino]­meth­yl}phenol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331856/
https://www.ncbi.nlm.nih.gov/pubmed/25705442
http://dx.doi.org/10.1107/S2056989014026309
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