Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one

The title compound, C(27)H(26)O(3), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings, and the dihedral angle between the pla...

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Autores principales: Sathya, S., Reuben Jonathan, D., Sidharthan, J., Vasanthi, R., Usha, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331857/
https://www.ncbi.nlm.nih.gov/pubmed/25705439
http://dx.doi.org/10.1107/S2056989014025390
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author Sathya, S.
Reuben Jonathan, D.
Sidharthan, J.
Vasanthi, R.
Usha, G.
author_facet Sathya, S.
Reuben Jonathan, D.
Sidharthan, J.
Vasanthi, R.
Usha, G.
author_sort Sathya, S.
collection PubMed
description The title compound, C(27)H(26)O(3), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings, and the dihedral angle between the planes of the terminal benzene rings is 51.49 (17)°. The corresponding values for mol­ecule B are 75.18 (14), 58.11 (16) and 47.91 (16)°, respectively. The cyclo­hexene ring adopts an envelope conformation in both mol­ecules, with the C atom to which is attached the central benzene ring as the flap. The crystal packing, is stabilized by C—H⋯π inter­actions.
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spelling pubmed-43318572015-02-20 Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one Sathya, S. Reuben Jonathan, D. Sidharthan, J. Vasanthi, R. Usha, G. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(27)H(26)O(3), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings, and the dihedral angle between the planes of the terminal benzene rings is 51.49 (17)°. The corresponding values for mol­ecule B are 75.18 (14), 58.11 (16) and 47.91 (16)°, respectively. The cyclo­hexene ring adopts an envelope conformation in both mol­ecules, with the C atom to which is attached the central benzene ring as the flap. The crystal packing, is stabilized by C—H⋯π inter­actions. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331857/ /pubmed/25705439 http://dx.doi.org/10.1107/S2056989014025390 Text en © Sathya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sathya, S.
Reuben Jonathan, D.
Sidharthan, J.
Vasanthi, R.
Usha, G.
Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title_full Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title_fullStr Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title_full_unstemmed Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title_short Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
title_sort crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331857/
https://www.ncbi.nlm.nih.gov/pubmed/25705439
http://dx.doi.org/10.1107/S2056989014025390
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