Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)

In the title compound, [UO(2)(C(5)H(7)O(2))(2)(C(14)H(15)N)], the uran­yl(VI) unit ([O=U=O](2+)) is coordinated to two acetyl­acetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) mol­ecule. The geometry around the U atom is UNO(6) penta­gonal–bipyramidal; two uran­yl(VI) O atoms ar...

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Detalles Bibliográficos
Autores principales: Kawasaki, Takeshi, Kitazawa, Takafumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331861/
https://www.ncbi.nlm.nih.gov/pubmed/25705446
http://dx.doi.org/10.1107/S2056989014026607
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author Kawasaki, Takeshi
Kitazawa, Takafumi
author_facet Kawasaki, Takeshi
Kitazawa, Takafumi
author_sort Kawasaki, Takeshi
collection PubMed
description In the title compound, [UO(2)(C(5)H(7)O(2))(2)(C(14)H(15)N)], the uran­yl(VI) unit ([O=U=O](2+)) is coordinated to two acetyl­acetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) mol­ecule. The geometry around the U atom is UNO(6) penta­gonal–bipyramidal; two uran­yl(VI) O atoms are located at the axial positions, whereas four O atoms from two chelating bidentate acac ligands and one N atom of a ppp ligand form the equatorial plane.
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spelling pubmed-43318612015-02-20 Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI) Kawasaki, Takeshi Kitazawa, Takafumi Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [UO(2)(C(5)H(7)O(2))(2)(C(14)H(15)N)], the uran­yl(VI) unit ([O=U=O](2+)) is coordinated to two acetyl­acetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) mol­ecule. The geometry around the U atom is UNO(6) penta­gonal–bipyramidal; two uran­yl(VI) O atoms are located at the axial positions, whereas four O atoms from two chelating bidentate acac ligands and one N atom of a ppp ligand form the equatorial plane. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331861/ /pubmed/25705446 http://dx.doi.org/10.1107/S2056989014026607 Text en © Kawasaki and Kitazawa 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kawasaki, Takeshi
Kitazawa, Takafumi
Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title_full Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title_fullStr Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title_full_unstemmed Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title_short Crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)
title_sort crystal structure of dioxidobis(pentane-2,4-dionato-κ(2) o,o′)[1-phenyl-3-(pyridin-4-yl)propane-κn]uranium(vi)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331861/
https://www.ncbi.nlm.nih.gov/pubmed/25705446
http://dx.doi.org/10.1107/S2056989014026607
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AT kitazawatakafumi crystalstructureofdioxidobispentane24dionatok2oo1phenyl3pyridin4ylpropaneknuraniumvi

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