Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]

The title compound, {[Li(C(5)H(3)N(2)O(2))(H(2)O)]·0.5H(2)O}(n), comprises four symmetry-independent Li(C(5)H(3)N(2)O(2))(H(2)O) units which form mol­ecular ribbons running along the c-axis direction. Within each ribbon, the ligand mol­ecule, acting in a μ(2)-mode, bridges two adjacent Li(+) cations...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331868/
https://www.ncbi.nlm.nih.gov/pubmed/25705456
http://dx.doi.org/10.1107/S2056989014026735
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The title compound, {[Li(C(5)H(3)N(2)O(2))(H(2)O)]·0.5H(2)O}(n), comprises four symmetry-independent Li(C(5)H(3)N(2)O(2))(H(2)O) units which form mol­ecular ribbons running along the c-axis direction. Within each ribbon, the ligand mol­ecule, acting in a μ(2)-mode, bridges two adjacent Li(+) cations using both of its N,O-bonding sites. The coordination environment of each of the four Li(+) cations can be described alternatively as either slightly distorted trigonal–bipyramidal or slightly distorted square–pyramidal. The ribbons are inter­connected by a network of O—H⋯O hydrogen bonds.
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spelling pubmed-43318682015-02-20 Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {[Li(C(5)H(3)N(2)O(2))(H(2)O)]·0.5H(2)O}(n), comprises four symmetry-independent Li(C(5)H(3)N(2)O(2))(H(2)O) units which form mol­ecular ribbons running along the c-axis direction. Within each ribbon, the ligand mol­ecule, acting in a μ(2)-mode, bridges two adjacent Li(+) cations using both of its N,O-bonding sites. The coordination environment of each of the four Li(+) cations can be described alternatively as either slightly distorted trigonal–bipyramidal or slightly distorted square–pyramidal. The ribbons are inter­connected by a network of O—H⋯O hydrogen bonds. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331868/ /pubmed/25705456 http://dx.doi.org/10.1107/S2056989014026735 Text en © Starosta and Leciejewicz 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Starosta, Wojciech
Leciejewicz, Janusz
Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title_full Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title_fullStr Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title_full_unstemmed Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title_short Crystal structure of catena-poly[[[aqua­lithium(I)]-μ-pyrimidine-2-carboxyl­ato-κ(4) N (1),O (2):N (3),O (2′)] hemihydrate]
title_sort crystal structure of catena-poly[[[aqua­lithium(i)]-μ-pyrimidine-2-carboxyl­ato-κ(4) n (1),o (2):n (3),o (2′)] hemihydrate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331868/
https://www.ncbi.nlm.nih.gov/pubmed/25705456
http://dx.doi.org/10.1107/S2056989014026735
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