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Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate

The asymmetric unit of the title compound, C(15)H(16)N(2)·C(4)H(8)O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH(2) group lie to the same side of th...

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Detalles Bibliográficos
Autores principales: Zhao, Jian-Ping, Liu, Rui-Qin, Jiang, Zhi-Hao, Bai, Sheng-Di
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331870/
https://www.ncbi.nlm.nih.gov/pubmed/25705489
http://dx.doi.org/10.1107/S2056989014026255
Descripción
Sumario:The asymmetric unit of the title compound, C(15)H(16)N(2)·C(4)H(8)O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH(2) group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (mol­ecule A) and 58.88 (6) ° (mol­ecule B). In the crystal, N—H⋯N hydrogen bonds link the amidine mol­ecules into [100] C(4) chains of alternating A and B mol­ecules. Both amidine mol­ecules form an N—H⋯O hydrogen bond to an adjacent THF solvent mol­ecule.