Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate

The asymmetric unit of the title compound, C(15)H(16)N(2)·C(4)H(8)O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH(2) group lie to the same side of th...

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Autores principales: Zhao, Jian-Ping, Liu, Rui-Qin, Jiang, Zhi-Hao, Bai, Sheng-Di
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331870/
https://www.ncbi.nlm.nih.gov/pubmed/25705489
http://dx.doi.org/10.1107/S2056989014026255
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author Zhao, Jian-Ping
Liu, Rui-Qin
Jiang, Zhi-Hao
Bai, Sheng-Di
author_facet Zhao, Jian-Ping
Liu, Rui-Qin
Jiang, Zhi-Hao
Bai, Sheng-Di
author_sort Zhao, Jian-Ping
collection PubMed
description The asymmetric unit of the title compound, C(15)H(16)N(2)·C(4)H(8)O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH(2) group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (mol­ecule A) and 58.88 (6) ° (mol­ecule B). In the crystal, N—H⋯N hydrogen bonds link the amidine mol­ecules into [100] C(4) chains of alternating A and B mol­ecules. Both amidine mol­ecules form an N—H⋯O hydrogen bond to an adjacent THF solvent mol­ecule.
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spelling pubmed-43318702015-02-20 Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate Zhao, Jian-Ping Liu, Rui-Qin Jiang, Zhi-Hao Bai, Sheng-Di Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(15)H(16)N(2)·C(4)H(8)O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH(2) group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (mol­ecule A) and 58.88 (6) ° (mol­ecule B). In the crystal, N—H⋯N hydrogen bonds link the amidine mol­ecules into [100] C(4) chains of alternating A and B mol­ecules. Both amidine mol­ecules form an N—H⋯O hydrogen bond to an adjacent THF solvent mol­ecule. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331870/ /pubmed/25705489 http://dx.doi.org/10.1107/S2056989014026255 Text en © Zhao et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zhao, Jian-Ping
Liu, Rui-Qin
Jiang, Zhi-Hao
Bai, Sheng-Di
Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title_full Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title_fullStr Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title_full_unstemmed Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title_short Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
title_sort crystal structure of n′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331870/
https://www.ncbi.nlm.nih.gov/pubmed/25705489
http://dx.doi.org/10.1107/S2056989014026255
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