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Crystal structure of chlorfluazuron
The title compound (systematic name: 1-{3,5-dichloro-4-[3-chloro-5-(trifluoromethyl)pyridin-2-yloxy]phenyl}-3-(2,6-difluorobenzoyl)urea), C(20)H(9)Cl(3)F(5)N(3)O(3), is a benzoylphenylurea insecticide. The dihedral angles between the planes of the central dichlorophenyl and the terminal...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331875/ https://www.ncbi.nlm.nih.gov/pubmed/25705506 http://dx.doi.org/10.1107/S2056989014026632 |
Sumario: | The title compound (systematic name: 1-{3,5-dichloro-4-[3-chloro-5-(trifluoromethyl)pyridin-2-yloxy]phenyl}-3-(2,6-difluorobenzoyl)urea), C(20)H(9)Cl(3)F(5)N(3)O(3), is a benzoylphenylurea insecticide. The dihedral angles between the planes of the central dichlorophenyl and the terminal difluorophenyl and chloropyridyl rings are 79.51 (6) and 78.84 6)°, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link adjacent molecules, forming R (2) (2)(8) inversion dimers. In addition, the dimers are linked by short F⋯Cl [3.1060 (16) Å] and Cl⋯Cl [3.2837 (7) Å] contacts, as well as weak intermolecular π–π interactions [ring centroid separation = 3.6100 (11) and 3.7764 (13) Å], resulting in a two-dimensional architecture parallel to (111). |
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