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Crystal structure of chlorfluazuron

The title compound (systematic name: 1-{3,5-di­chloro-4-[3-chloro-5-(tri­fluoro­meth­yl)pyridin-2-yl­oxy]phen­yl}-3-(2,6-difluoro­benzo­yl)urea), C(20)H(9)Cl(3)F(5)N(3)O(3), is a benzoyl­phenyl­urea insecticide. The dihedral angles between the planes of the central di­chloro­phenyl and the terminal...

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Detalles Bibliográficos
Autores principales: Cho, Seonghwa, Kim, Jineun, Lee, Sangjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331875/
https://www.ncbi.nlm.nih.gov/pubmed/25705506
http://dx.doi.org/10.1107/S2056989014026632
Descripción
Sumario:The title compound (systematic name: 1-{3,5-di­chloro-4-[3-chloro-5-(tri­fluoro­meth­yl)pyridin-2-yl­oxy]phen­yl}-3-(2,6-difluoro­benzo­yl)urea), C(20)H(9)Cl(3)F(5)N(3)O(3), is a benzoyl­phenyl­urea insecticide. The dihedral angles between the planes of the central di­chloro­phenyl and the terminal di­fluoro­phenyl and chloro­pyridyl rings are 79.51 (6) and 78.84 6)°, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link adjacent mol­ecules, forming R (2) (2)(8) inversion dimers. In addition, the dimers are linked by short F⋯Cl [3.1060 (16) Å] and Cl⋯Cl [3.2837 (7) Å] contacts, as well as weak inter­molecular π–π inter­actions [ring centroid separation = 3.6100 (11) and 3.7764 (13) Å], resulting in a two-dimensional architecture parallel to (111).