Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)­oxy]naphthalen-1-yl}-N-(4-fluoro­phen­yl)methanimine

In the title compound, C(22)H(21)FNO(3)P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å....

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Detalles Bibliográficos
Autores principales: Said, Musa A., Al Belewi, Bayan L., Hughes, David L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331876/
https://www.ncbi.nlm.nih.gov/pubmed/25705459
http://dx.doi.org/10.1107/S2056989014026838
Descripción
Sumario:In the title compound, C(22)H(21)FNO(3)P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å. The six-membered ring which includes the P atom has a chair conformation. The fluoro­phenyl ring is inclined to the naphthalene ring system by 24.42 (7)°. In the crystal, mol­ecules are linked via C—H⋯π inter­actions, forming slabs lying parallel to (10-1).

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