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Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine
In the title compound, C(22)H(21)FNO(3)P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331876/ https://www.ncbi.nlm.nih.gov/pubmed/25705459 http://dx.doi.org/10.1107/S2056989014026838 |
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| author | Said, Musa A. Al Belewi, Bayan L. Hughes, David L. |
| author_facet | Said, Musa A. Al Belewi, Bayan L. Hughes, David L. |
| author_sort | Said, Musa A. |
| collection | PubMed |
| description | In the title compound, C(22)H(21)FNO(3)P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å. The six-membered ring which includes the P atom has a chair conformation. The fluorophenyl ring is inclined to the naphthalene ring system by 24.42 (7)°. In the crystal, molecules are linked via C—H⋯π interactions, forming slabs lying parallel to (10-1). |
| format | Online Article Text |
| id | pubmed-4331876 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-43318762015-02-20 Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine Said, Musa A. Al Belewi, Bayan L. Hughes, David L. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(22)H(21)FNO(3)P, a 1,3,2-dioxaphosphinan-2-yloxy derivative, three O atoms are bonded in a trigonal–pyramidal manner to the P atom. The exocyclic P—O bond is significantly longer than the two endocyclic P—O bonds, viz. 1.6678 (12) Å compared to 1.6046 (13) and 1.6096 (12) Å. The six-membered ring which includes the P atom has a chair conformation. The fluorophenyl ring is inclined to the naphthalene ring system by 24.42 (7)°. In the crystal, molecules are linked via C—H⋯π interactions, forming slabs lying parallel to (10-1). International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331876/ /pubmed/25705459 http://dx.doi.org/10.1107/S2056989014026838 Text en © Said et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Said, Musa A. Al Belewi, Bayan L. Hughes, David L. Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title | Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title_full | Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title_fullStr | Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title_full_unstemmed | Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title_short | Crystal structure of (E)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-N-(4-fluorophenyl)methanimine |
| title_sort | crystal structure of (e)-1-{2-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]naphthalen-1-yl}-n-(4-fluorophenyl)methanimine |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331876/ https://www.ncbi.nlm.nih.gov/pubmed/25705459 http://dx.doi.org/10.1107/S2056989014026838 |
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