1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)

The whole molecule of the title Schiff base compound, C(28)H(28)N(2)O(2), is generated by inversion symmetry. It is formed from two units of ortho-hy­droxy­naphthaldehyde bridged with 1,6-di­amino­hexane. The N atoms are protonated and, thus, the structure is a bis-zwitterionic compound in the solid...

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Detalles Bibliográficos
Autores principales: Ouari, Kamel, Bendia, Sabrina, Merzougui, Moufida, Bailly, Corinne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331877/
https://www.ncbi.nlm.nih.gov/pubmed/25705504
http://dx.doi.org/10.1107/S2056989014027236
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author Ouari, Kamel
Bendia, Sabrina
Merzougui, Moufida
Bailly, Corinne
author_facet Ouari, Kamel
Bendia, Sabrina
Merzougui, Moufida
Bailly, Corinne
author_sort Ouari, Kamel
collection PubMed
description The whole molecule of the title Schiff base compound, C(28)H(28)N(2)O(2), is generated by inversion symmetry. It is formed from two units of ortho-hy­droxy­naphthaldehyde bridged with 1,6-di­amino­hexane. The N atoms are protonated and, thus, the structure is a bis-zwitterionic compound in the solid state. The zwitterion shows strong intra­molecular N—H⋯O hydrogen bonds between the iminium N and the naphthaleno­late O atoms.
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spelling pubmed-43318772015-02-20 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate) Ouari, Kamel Bendia, Sabrina Merzougui, Moufida Bailly, Corinne Acta Crystallogr E Crystallogr Commun Data Reports The whole molecule of the title Schiff base compound, C(28)H(28)N(2)O(2), is generated by inversion symmetry. It is formed from two units of ortho-hy­droxy­naphthaldehyde bridged with 1,6-di­amino­hexane. The N atoms are protonated and, thus, the structure is a bis-zwitterionic compound in the solid state. The zwitterion shows strong intra­molecular N—H⋯O hydrogen bonds between the iminium N and the naphthaleno­late O atoms. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331877/ /pubmed/25705504 http://dx.doi.org/10.1107/S2056989014027236 Text en © Ouari et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ouari, Kamel
Bendia, Sabrina
Merzougui, Moufida
Bailly, Corinne
1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title_full 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title_fullStr 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title_full_unstemmed 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title_short 1,1′-{(Hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
title_sort 1,1′-{(hexane-1,6-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(naphthalen-2-olate)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331877/
https://www.ncbi.nlm.nih.gov/pubmed/25705504
http://dx.doi.org/10.1107/S2056989014027236
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AT merzouguimoufida 11hexane16diylbisazaniumylylidenemethanylylidenebisnaphthalen2olate
AT baillycorinne 11hexane16diylbisazaniumylylidenemethanylylidenebisnaphthalen2olate

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