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Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride

In the title compound, C(7)H(9)NO(5), alternative name N-carb­oxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in...

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Detalles Bibliográficos
Autores principales: Kanazawa, Hitoshi, Inada, Aya, Sakon, Aya, Uekusa, Hidehiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331887/
https://www.ncbi.nlm.nih.gov/pubmed/25705448
http://dx.doi.org/10.1107/S2056989014026917
Descripción
Sumario:In the title compound, C(7)H(9)NO(5), alternative name N-carb­oxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a-axis direction. The tapes are linked by C—H⋯O inter­actions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C⋯O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state.