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Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride

In the title compound, C(7)H(9)NO(5), alternative name N-carb­oxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in...

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Autores principales: Kanazawa, Hitoshi, Inada, Aya, Sakon, Aya, Uekusa, Hidehiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331887/
https://www.ncbi.nlm.nih.gov/pubmed/25705448
http://dx.doi.org/10.1107/S2056989014026917
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author Kanazawa, Hitoshi
Inada, Aya
Sakon, Aya
Uekusa, Hidehiro
author_facet Kanazawa, Hitoshi
Inada, Aya
Sakon, Aya
Uekusa, Hidehiro
author_sort Kanazawa, Hitoshi
collection PubMed
description In the title compound, C(7)H(9)NO(5), alternative name N-carb­oxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a-axis direction. The tapes are linked by C—H⋯O inter­actions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C⋯O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state.
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spelling pubmed-43318872015-02-20 Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride Kanazawa, Hitoshi Inada, Aya Sakon, Aya Uekusa, Hidehiro Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(7)H(9)NO(5), alternative name N-carb­oxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a-axis direction. The tapes are linked by C—H⋯O inter­actions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C⋯O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331887/ /pubmed/25705448 http://dx.doi.org/10.1107/S2056989014026917 Text en © Kanazawa et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kanazawa, Hitoshi
Inada, Aya
Sakon, Aya
Uekusa, Hidehiro
Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title_full Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title_fullStr Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title_full_unstemmed Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title_short Crystal structure of γ-methyl l-glutamate N-carb­oxy anhydride
title_sort crystal structure of γ-methyl l-glutamate n-carb­oxy anhydride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331887/
https://www.ncbi.nlm.nih.gov/pubmed/25705448
http://dx.doi.org/10.1107/S2056989014026917
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