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Crystal structure of γ-methyl l-glutamate N-carboxy anhydride
In the title compound, C(7)H(9)NO(5), alternative name N-carboxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, molecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331887/ https://www.ncbi.nlm.nih.gov/pubmed/25705448 http://dx.doi.org/10.1107/S2056989014026917 |
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author | Kanazawa, Hitoshi Inada, Aya Sakon, Aya Uekusa, Hidehiro |
author_facet | Kanazawa, Hitoshi Inada, Aya Sakon, Aya Uekusa, Hidehiro |
author_sort | Kanazawa, Hitoshi |
collection | PubMed |
description | In the title compound, C(7)H(9)NO(5), alternative name N-carboxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, molecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a-axis direction. The tapes are linked by C—H⋯O interactions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C⋯O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state. |
format | Online Article Text |
id | pubmed-4331887 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43318872015-02-20 Crystal structure of γ-methyl l-glutamate N-carboxy anhydride Kanazawa, Hitoshi Inada, Aya Sakon, Aya Uekusa, Hidehiro Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(7)H(9)NO(5), alternative name N-carboxy-l-glutamic anhydride γ-methyl ester, the oxazolidine ring is essentially planar with a maximum deviation of 0.020 (3) Å. In the crystal, molecules are linked by N—H⋯O hydrogen bonds between the imino group and the carbonyl O atom in the methyl ester group, forming a tape structure along the a-axis direction. The tapes are linked by C—H⋯O interactions into a sheet parallel to the ac plane. The tapes are also stacked along the b axis with short contacts between the oxazolidine rings [C⋯O contact distances = 2.808 (4)–3.060 (4) Å], so that the oxazolidine rings are arranged in a layer parallel to the ab plane. This arrangement of the oxazolidine rings is very preferable for the polymerization of the title compound in the solid state. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331887/ /pubmed/25705448 http://dx.doi.org/10.1107/S2056989014026917 Text en © Kanazawa et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Kanazawa, Hitoshi Inada, Aya Sakon, Aya Uekusa, Hidehiro Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title | Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title_full | Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title_fullStr | Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title_full_unstemmed | Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title_short | Crystal structure of γ-methyl l-glutamate N-carboxy anhydride |
title_sort | crystal structure of γ-methyl l-glutamate n-carboxy anhydride |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331887/ https://www.ncbi.nlm.nih.gov/pubmed/25705448 http://dx.doi.org/10.1107/S2056989014026917 |
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