Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one

In the title compound, C(22)H(17)NO(3), the mol­ecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings...

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Autores principales: Vidhyasagar, T., Rajeswari, K., Shanthi, D., Kayalvizhi, M., Vasuki, G., Thiruvalluvar, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331888/
https://www.ncbi.nlm.nih.gov/pubmed/25705513
http://dx.doi.org/10.1107/S2056989014027443
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author Vidhyasagar, T.
Rajeswari, K.
Shanthi, D.
Kayalvizhi, M.
Vasuki, G.
Thiruvalluvar, A.
author_facet Vidhyasagar, T.
Rajeswari, K.
Shanthi, D.
Kayalvizhi, M.
Vasuki, G.
Thiruvalluvar, A.
author_sort Vidhyasagar, T.
collection PubMed
description In the title compound, C(22)H(17)NO(3), the mol­ecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings being 38.02 (15)°. The dihedral angle between the nitro­phenyl ring and the inner benzene ring is 5.29 (16)°. In the crystal, mol­ecules are linked by two weak C—H⋯π inter­actions, forming rectangular tubes propagating along the b-axis direction.
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spelling pubmed-43318882015-02-20 Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one Vidhyasagar, T. Rajeswari, K. Shanthi, D. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(22)H(17)NO(3), the mol­ecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings being 38.02 (15)°. The dihedral angle between the nitro­phenyl ring and the inner benzene ring is 5.29 (16)°. In the crystal, mol­ecules are linked by two weak C—H⋯π inter­actions, forming rectangular tubes propagating along the b-axis direction. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331888/ /pubmed/25705513 http://dx.doi.org/10.1107/S2056989014027443 Text en © Vidhyasagar et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Vidhyasagar, T.
Rajeswari, K.
Shanthi, D.
Kayalvizhi, M.
Vasuki, G.
Thiruvalluvar, A.
Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title_full Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title_fullStr Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title_full_unstemmed Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title_short Crystal structure of (E)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
title_sort crystal structure of (e)-1-(4′-methyl-[1,1′-biphen­yl]-4-yl)-3-(3-nitro­phen­yl)prop-2-en-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331888/
https://www.ncbi.nlm.nih.gov/pubmed/25705513
http://dx.doi.org/10.1107/S2056989014027443
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