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Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one
In the title compound, C(22)H(17)NO(3), the molecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331888/ https://www.ncbi.nlm.nih.gov/pubmed/25705513 http://dx.doi.org/10.1107/S2056989014027443 |
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author | Vidhyasagar, T. Rajeswari, K. Shanthi, D. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. |
author_facet | Vidhyasagar, T. Rajeswari, K. Shanthi, D. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. |
author_sort | Vidhyasagar, T. |
collection | PubMed |
description | In the title compound, C(22)H(17)NO(3), the molecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings being 38.02 (15)°. The dihedral angle between the nitrophenyl ring and the inner benzene ring is 5.29 (16)°. In the crystal, molecules are linked by two weak C—H⋯π interactions, forming rectangular tubes propagating along the b-axis direction. |
format | Online Article Text |
id | pubmed-4331888 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43318882015-02-20 Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one Vidhyasagar, T. Rajeswari, K. Shanthi, D. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(22)H(17)NO(3), the molecule has an E conformation about the C=C bond, and the C—C=C—C torsion angle is −177.7 (3)°. The planes of the terminal benzene rings are twisted by 41.62 (16)°, while the biphenyl unit is non-planar, the dihedral angle between the planes of the rings being 38.02 (15)°. The dihedral angle between the nitrophenyl ring and the inner benzene ring is 5.29 (16)°. In the crystal, molecules are linked by two weak C—H⋯π interactions, forming rectangular tubes propagating along the b-axis direction. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331888/ /pubmed/25705513 http://dx.doi.org/10.1107/S2056989014027443 Text en © Vidhyasagar et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Vidhyasagar, T. Rajeswari, K. Shanthi, D. Kayalvizhi, M. Vasuki, G. Thiruvalluvar, A. Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title | Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title_full | Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title_fullStr | Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title_full_unstemmed | Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title_short | Crystal structure of (E)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
title_sort | crystal structure of (e)-1-(4′-methyl-[1,1′-biphenyl]-4-yl)-3-(3-nitrophenyl)prop-2-en-1-one |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331888/ https://www.ncbi.nlm.nih.gov/pubmed/25705513 http://dx.doi.org/10.1107/S2056989014027443 |
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