Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione

In the title compound, C(17)H(11)Cl(6)NO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short inter­molecular C⋯O distance of 3.017 (3) Å revea...

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Autores principales: Liu, He, Zhong, Jia-liang, Sun, Wen-xia, Gong, Yan-qing, Liu, Li-hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331899/
https://www.ncbi.nlm.nih.gov/pubmed/25705480
http://dx.doi.org/10.1107/S2056989014025961
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author Liu, He
Zhong, Jia-liang
Sun, Wen-xia
Gong, Yan-qing
Liu, Li-hong
author_facet Liu, He
Zhong, Jia-liang
Sun, Wen-xia
Gong, Yan-qing
Liu, Li-hong
author_sort Liu, He
collection PubMed
description In the title compound, C(17)H(11)Cl(6)NO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short inter­molecular C⋯O distance of 3.017 (3) Å reveals that one carbonyl group is involved in dipole–dipole inter­actions, which link two adjacent enanti­omers into an inversion dimer. Another carbonyl group provides an acceptor for the weak inter­molecular C—H⋯O hydrogen bonds which link these dimers into layers parallel to (011).
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spelling pubmed-43318992015-02-20 Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione Liu, He Zhong, Jia-liang Sun, Wen-xia Gong, Yan-qing Liu, Li-hong Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(11)Cl(6)NO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short inter­molecular C⋯O distance of 3.017 (3) Å reveals that one carbonyl group is involved in dipole–dipole inter­actions, which link two adjacent enanti­omers into an inversion dimer. Another carbonyl group provides an acceptor for the weak inter­molecular C—H⋯O hydrogen bonds which link these dimers into layers parallel to (011). International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331899/ /pubmed/25705480 http://dx.doi.org/10.1107/S2056989014025961 Text en © Liu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Liu, He
Zhong, Jia-liang
Sun, Wen-xia
Gong, Yan-qing
Liu, Li-hong
Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_full Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_fullStr Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_full_unstemmed Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_short Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_sort crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331899/
https://www.ncbi.nlm.nih.gov/pubmed/25705480
http://dx.doi.org/10.1107/S2056989014025961
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