Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione

In the title compound, C(17)H(12)Cl(4)FNO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C—H⋯O hydrogen bond. The other meth...

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Detalles Bibliográficos
Autores principales: Zhong, Jia-liang, Hou, Jia-wei, Liu, Li-hong, Liu, He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331900/
https://www.ncbi.nlm.nih.gov/pubmed/25705492
http://dx.doi.org/10.1107/S2056989014026279
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author Zhong, Jia-liang
Hou, Jia-wei
Liu, Li-hong
Liu, He
author_facet Zhong, Jia-liang
Hou, Jia-wei
Liu, Li-hong
Liu, He
author_sort Zhong, Jia-liang
collection PubMed
description In the title compound, C(17)H(12)Cl(4)FNO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C—H⋯O hydrogen bond. The other methine groups participates in a C—H⋯F inter­action to the same adjacent mol­ecule. Together, these generate [010] chains.
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spelling pubmed-43319002015-02-20 Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione Zhong, Jia-liang Hou, Jia-wei Liu, Li-hong Liu, He Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(12)Cl(4)FNO(4), the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C—H⋯O hydrogen bond. The other methine groups participates in a C—H⋯F inter­action to the same adjacent mol­ecule. Together, these generate [010] chains. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331900/ /pubmed/25705492 http://dx.doi.org/10.1107/S2056989014026279 Text en © Zhong et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zhong, Jia-liang
Hou, Jia-wei
Liu, Li-hong
Liu, He
Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_full Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_fullStr Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_full_unstemmed Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_short Crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
title_sort crystal structure of 1,7,8,9-tetra­chloro-4-(2-fluoro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.0(2,6)]dec-8-ene-3,5-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331900/
https://www.ncbi.nlm.nih.gov/pubmed/25705492
http://dx.doi.org/10.1107/S2056989014026279
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