Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone

The title compound, C(21)H(16)N(2)O, has an almost planar (r.m.s. deviation = 0.0074 Å) 1,2-di­benzyl­idenehydrazine backbone with an approximately orthogonal almost planar (r.m.s. deviation = 0.0368 Å) phenyl­ethanone substituent on one of the imine C atoms. The dihedral angle between the two mean...

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Autores principales: Bouchama, Abdelaziz, Yahiaoui, Messaoud, Chiter, Chaabane, Setifi, Zouaoui, Simpson, Jim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331908/
https://www.ncbi.nlm.nih.gov/pubmed/25705444
http://dx.doi.org/10.1107/S2056989014026358
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author Bouchama, Abdelaziz
Yahiaoui, Messaoud
Chiter, Chaabane
Setifi, Zouaoui
Simpson, Jim
author_facet Bouchama, Abdelaziz
Yahiaoui, Messaoud
Chiter, Chaabane
Setifi, Zouaoui
Simpson, Jim
author_sort Bouchama, Abdelaziz
collection PubMed
description The title compound, C(21)H(16)N(2)O, has an almost planar (r.m.s. deviation = 0.0074 Å) 1,2-di­benzyl­idenehydrazine backbone with an approximately orthogonal almost planar (r.m.s. deviation = 0.0368 Å) phenyl­ethanone substituent on one of the imine C atoms. The dihedral angle between the two mean planes is 76.99 (4)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds and C—H⋯π contacts, forming a three-dimensional structure with mol­ecules stacked along the a-axis direction.
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spelling pubmed-43319082015-02-20 Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone Bouchama, Abdelaziz Yahiaoui, Messaoud Chiter, Chaabane Setifi, Zouaoui Simpson, Jim Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(21)H(16)N(2)O, has an almost planar (r.m.s. deviation = 0.0074 Å) 1,2-di­benzyl­idenehydrazine backbone with an approximately orthogonal almost planar (r.m.s. deviation = 0.0368 Å) phenyl­ethanone substituent on one of the imine C atoms. The dihedral angle between the two mean planes is 76.99 (4)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds and C—H⋯π contacts, forming a three-dimensional structure with mol­ecules stacked along the a-axis direction. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331908/ /pubmed/25705444 http://dx.doi.org/10.1107/S2056989014026358 Text en © Bouchama et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bouchama, Abdelaziz
Yahiaoui, Messaoud
Chiter, Chaabane
Setifi, Zouaoui
Simpson, Jim
Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title_full Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title_fullStr Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title_full_unstemmed Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title_short Crystal structure of (Z)-2-[(E)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
title_sort crystal structure of (z)-2-[(e)-2-benzyl­idene­hydrazin-1-yl­idene]-1,2-di­phenyl­ethanone
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331908/
https://www.ncbi.nlm.nih.gov/pubmed/25705444
http://dx.doi.org/10.1107/S2056989014026358
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