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Crystal structure of bis(2,2′-bipyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate
In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331911/ https://www.ncbi.nlm.nih.gov/pubmed/25705473 http://dx.doi.org/10.1107/S205698901402516X |
Sumario: | In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmetric unit consists of one Mn(II) cation, two thiocyanate anions and two 2,2′-bipyridine ligands, as well as two non-coordinating 2,2′-bipyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)(2)(C(10)H(8)N(2))(2)] complex molecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bipyridine molecules are located. Apart from van der Waals forces, there are no remarkable intermolecular interactions present in the crystal structure. |
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