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Crystal structure of bis(2,2′-bipyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate
In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331911/ https://www.ncbi.nlm.nih.gov/pubmed/25705473 http://dx.doi.org/10.1107/S205698901402516X |
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author | Suckert, Stefan Jess, Inke Näther, Christian |
author_facet | Suckert, Stefan Jess, Inke Näther, Christian |
author_sort | Suckert, Stefan |
collection | PubMed |
description | In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmetric unit consists of one Mn(II) cation, two thiocyanate anions and two 2,2′-bipyridine ligands, as well as two non-coordinating 2,2′-bipyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)(2)(C(10)H(8)N(2))(2)] complex molecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bipyridine molecules are located. Apart from van der Waals forces, there are no remarkable intermolecular interactions present in the crystal structure. |
format | Online Article Text |
id | pubmed-4331911 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43319112015-02-20 Crystal structure of bis(2,2′-bipyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmetric unit consists of one Mn(II) cation, two thiocyanate anions and two 2,2′-bipyridine ligands, as well as two non-coordinating 2,2′-bipyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)(2)(C(10)H(8)N(2))(2)] complex molecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bipyridine molecules are located. Apart from van der Waals forces, there are no remarkable intermolecular interactions present in the crystal structure. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331911/ /pubmed/25705473 http://dx.doi.org/10.1107/S205698901402516X Text en © Suckert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Suckert, Stefan Jess, Inke Näther, Christian Crystal structure of bis(2,2′-bipyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title | Crystal structure of bis(2,2′-bipyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title_full | Crystal structure of bis(2,2′-bipyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title_fullStr | Crystal structure of bis(2,2′-bipyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title_full_unstemmed | Crystal structure of bis(2,2′-bipyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title_short | Crystal structure of bis(2,2′-bipyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate |
title_sort | crystal structure of bis(2,2′-bipyridine-κ(2)
n,n′)bis(thiocyanato-κn)manganese(ii) 2,2′-bipyridine monosolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331911/ https://www.ncbi.nlm.nih.gov/pubmed/25705473 http://dx.doi.org/10.1107/S205698901402516X |
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