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Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate

In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordin­ated in an all-cis configuration by two N-bound thio­cyanate anions and two 2,2′-bi­pyridine ligands within a slightly distorted octa­hedral environment. The asymmet...

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Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331911/
https://www.ncbi.nlm.nih.gov/pubmed/25705473
http://dx.doi.org/10.1107/S205698901402516X
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author Suckert, Stefan
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordin­ated in an all-cis configuration by two N-bound thio­cyanate anions and two 2,2′-bi­pyridine ligands within a slightly distorted octa­hedral environment. The asymmetric unit consists of one Mn(II) cation, two thio­cyanate anions and two 2,2′-bi­pyridine ligands, as well as two non-coordinating 2,2′-bi­pyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)(2)(C(10)H(8)N(2))(2)] complex mol­ecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bi­pyridine mol­ecules are located. Apart from van der Waals forces, there are no remarkable inter­molecular inter­actions present in the crystal structure.
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spelling pubmed-43319112015-02-20 Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports In the crystal structure of the mononuclear title compound, [Mn(NCS)(2)(C(10)H(8)N(2))(2)]·C(10)H(8)N(2), the Mn(II) cation is coordin­ated in an all-cis configuration by two N-bound thio­cyanate anions and two 2,2′-bi­pyridine ligands within a slightly distorted octa­hedral environment. The asymmetric unit consists of one Mn(II) cation, two thio­cyanate anions and two 2,2′-bi­pyridine ligands, as well as two non-coordinating 2,2′-bi­pyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)(2)(C(10)H(8)N(2))(2)] complex mol­ecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bi­pyridine mol­ecules are located. Apart from van der Waals forces, there are no remarkable inter­molecular inter­actions present in the crystal structure. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331911/ /pubmed/25705473 http://dx.doi.org/10.1107/S205698901402516X Text en © Suckert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Suckert, Stefan
Jess, Inke
Näther, Christian
Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title_full Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title_fullStr Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title_full_unstemmed Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title_short Crystal structure of bis­(2,2′-bi­pyridine-κ(2) N,N′)bis­(thio­cyanato-κN)mang­anese(II) 2,2′-bi­pyridine monosolvate
title_sort crystal structure of bis­(2,2′-bi­pyridine-κ(2) n,n′)bis­(thio­cyanato-κn)mang­anese(ii) 2,2′-bi­pyridine monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331911/
https://www.ncbi.nlm.nih.gov/pubmed/25705473
http://dx.doi.org/10.1107/S205698901402516X
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