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Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione
In the title isoquinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,4-trione ring make a dihedral angle...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331915/ https://www.ncbi.nlm.nih.gov/pubmed/25705509 http://dx.doi.org/10.1107/S2056989014025997 |
Sumario: | In the title isoquinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,4-trione ring make a dihedral angle of 82.06 (6)°. In the crystal, molecules are linked into chains extending along the bc plane via C—H⋯O hydrogen-bonding interactions, enclosing R (2) (2)(8) and R (2) (2)(10) loops. The chains are further connected by π–π stacking interations, with centroid-to-centroid distances of 3.9050 (7) Å, forming layers parallel to the b axis. |
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