Cargando…

Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione

In the title iso­quinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitro­gen-substituted C atom being the flap. The planes of the indane benzene ring and the iso­quinoline-1,3,4-trione ring make a dihedral angle...

Descripción completa

Detalles Bibliográficos
Autores principales: Ghalib, Raza Murad, Chidan Kumar, C. S., Hashim, Rokiah, Sulaiman, Othman, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331915/
https://www.ncbi.nlm.nih.gov/pubmed/25705509
http://dx.doi.org/10.1107/S2056989014025997
_version_ 1782357809957961728
author Ghalib, Raza Murad
Chidan Kumar, C. S.
Hashim, Rokiah
Sulaiman, Othman
Fun, Hoong-Kun
author_facet Ghalib, Raza Murad
Chidan Kumar, C. S.
Hashim, Rokiah
Sulaiman, Othman
Fun, Hoong-Kun
author_sort Ghalib, Raza Murad
collection PubMed
description In the title iso­quinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitro­gen-substituted C atom being the flap. The planes of the indane benzene ring and the iso­quinoline-1,3,4-trione ring make a dihedral angle of 82.06 (6)°. In the crystal, mol­ecules are linked into chains extending along the bc plane via C—H⋯O hydrogen-bonding inter­actions, enclosing R (2) (2)(8) and R (2) (2)(10) loops. The chains are further connected by π–π stacking inter­ations, with centroid-to-centroid distances of 3.9050 (7) Å, forming layers parallel to the b axis.
format Online
Article
Text
id pubmed-4331915
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43319152015-02-20 Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione Ghalib, Raza Murad Chidan Kumar, C. S. Hashim, Rokiah Sulaiman, Othman Fun, Hoong-Kun Acta Crystallogr E Crystallogr Commun Data Reports In the title iso­quinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitro­gen-substituted C atom being the flap. The planes of the indane benzene ring and the iso­quinoline-1,3,4-trione ring make a dihedral angle of 82.06 (6)°. In the crystal, mol­ecules are linked into chains extending along the bc plane via C—H⋯O hydrogen-bonding inter­actions, enclosing R (2) (2)(8) and R (2) (2)(10) loops. The chains are further connected by π–π stacking inter­ations, with centroid-to-centroid distances of 3.9050 (7) Å, forming layers parallel to the b axis. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331915/ /pubmed/25705509 http://dx.doi.org/10.1107/S2056989014025997 Text en © Ghalib et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ghalib, Raza Murad
Chidan Kumar, C. S.
Hashim, Rokiah
Sulaiman, Othman
Fun, Hoong-Kun
Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title_full Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title_fullStr Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title_full_unstemmed Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title_short Crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
title_sort crystal structure of 2-(1,3-dioxoindan-2-yl)iso­quinoline-1,3,4-trione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331915/
https://www.ncbi.nlm.nih.gov/pubmed/25705509
http://dx.doi.org/10.1107/S2056989014025997
work_keys_str_mv AT ghalibrazamurad crystalstructureof213dioxoindan2ylisoquinoline134trione
AT chidankumarcs crystalstructureof213dioxoindan2ylisoquinoline134trione
AT hashimrokiah crystalstructureof213dioxoindan2ylisoquinoline134trione
AT sulaimanothman crystalstructureof213dioxoindan2ylisoquinoline134trione
AT funhoongkun crystalstructureof213dioxoindan2ylisoquinoline134trione