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Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione
In the title isoquinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,4-trione ring make a dihedral angle...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331915/ https://www.ncbi.nlm.nih.gov/pubmed/25705509 http://dx.doi.org/10.1107/S2056989014025997 |
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author | Ghalib, Raza Murad Chidan Kumar, C. S. Hashim, Rokiah Sulaiman, Othman Fun, Hoong-Kun |
author_facet | Ghalib, Raza Murad Chidan Kumar, C. S. Hashim, Rokiah Sulaiman, Othman Fun, Hoong-Kun |
author_sort | Ghalib, Raza Murad |
collection | PubMed |
description | In the title isoquinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,4-trione ring make a dihedral angle of 82.06 (6)°. In the crystal, molecules are linked into chains extending along the bc plane via C—H⋯O hydrogen-bonding interactions, enclosing R (2) (2)(8) and R (2) (2)(10) loops. The chains are further connected by π–π stacking interations, with centroid-to-centroid distances of 3.9050 (7) Å, forming layers parallel to the b axis. |
format | Online Article Text |
id | pubmed-4331915 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43319152015-02-20 Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione Ghalib, Raza Murad Chidan Kumar, C. S. Hashim, Rokiah Sulaiman, Othman Fun, Hoong-Kun Acta Crystallogr E Crystallogr Commun Data Reports In the title isoquinoline-1,3,4-trione derivative, C(18)H(9)NO(5), the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,4-trione ring make a dihedral angle of 82.06 (6)°. In the crystal, molecules are linked into chains extending along the bc plane via C—H⋯O hydrogen-bonding interactions, enclosing R (2) (2)(8) and R (2) (2)(10) loops. The chains are further connected by π–π stacking interations, with centroid-to-centroid distances of 3.9050 (7) Å, forming layers parallel to the b axis. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331915/ /pubmed/25705509 http://dx.doi.org/10.1107/S2056989014025997 Text en © Ghalib et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Ghalib, Raza Murad Chidan Kumar, C. S. Hashim, Rokiah Sulaiman, Othman Fun, Hoong-Kun Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title | Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title_full | Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title_fullStr | Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title_full_unstemmed | Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title_short | Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
title_sort | crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331915/ https://www.ncbi.nlm.nih.gov/pubmed/25705509 http://dx.doi.org/10.1107/S2056989014025997 |
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