Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines

A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyrid...

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Detalles Bibliográficos
Autores principales: Helan, V., Gulevich, A. V., Gevorgyan, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4332698/
https://www.ncbi.nlm.nih.gov/pubmed/25705369
http://dx.doi.org/10.1039/c4sc03358b
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author Helan, V.
Gulevich, A. V.
Gevorgyan, V.
author_facet Helan, V.
Gulevich, A. V.
Gevorgyan, V.
author_sort Helan, V.
collection PubMed
description A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.
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spelling pubmed-43326982016-03-01 Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines Helan, V. Gulevich, A. V. Gevorgyan, V. Chem Sci Chemistry A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes. Royal Society of Chemistry 2015-03-01 2015-01-05 /pmc/articles/PMC4332698/ /pubmed/25705369 http://dx.doi.org/10.1039/c4sc03358b Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Helan, V.
Gulevich, A. V.
Gevorgyan, V.
Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title_full Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title_fullStr Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title_full_unstemmed Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title_short Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
title_sort cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4332698/
https://www.ncbi.nlm.nih.gov/pubmed/25705369
http://dx.doi.org/10.1039/c4sc03358b
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AT gevorgyanv cucatalyzedtransannulationreactionofpyridotriazoleswithterminalalkynesunderaerobicconditionsefficientsynthesisofindolizines

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