Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction

Singular value decomposition (SVD) analysis has important applications for time-dependent crystallographic data, extracting significant information. Herein, a successful application of SVD analysis of time-resolved powder diffraction data over the course of an in-situ photodimerization reaction of a...

Descripción completa

Detalles Bibliográficos
Autores principales: Mabied, Ahmed F., Nozawa, Shunsuke, Hoshino, Manabu, Tomita, Ayana, Sato, Tokushi, Adachi, Shin-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333817/
https://www.ncbi.nlm.nih.gov/pubmed/24763645
http://dx.doi.org/10.1107/S1600577514004366
_version_ 1782358102157295616
author Mabied, Ahmed F.
Nozawa, Shunsuke
Hoshino, Manabu
Tomita, Ayana
Sato, Tokushi
Adachi, Shin-ichi
author_facet Mabied, Ahmed F.
Nozawa, Shunsuke
Hoshino, Manabu
Tomita, Ayana
Sato, Tokushi
Adachi, Shin-ichi
author_sort Mabied, Ahmed F.
collection PubMed
description Singular value decomposition (SVD) analysis has important applications for time-dependent crystallographic data, extracting significant information. Herein, a successful application of SVD analysis of time-resolved powder diffraction data over the course of an in-situ photodimerization reaction of anthracene derivatives is introduced. SVD revealed significant results in the case of 9-methylanthracene and 1-chloroanthracene. The results support the formation of the 9-methylanthracene stable dimer phase and suggest the existence of an excimer state.
format Online
Article
Text
id pubmed-4333817
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43338172015-02-20 Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction Mabied, Ahmed F. Nozawa, Shunsuke Hoshino, Manabu Tomita, Ayana Sato, Tokushi Adachi, Shin-ichi J Synchrotron Radiat Research Papers Singular value decomposition (SVD) analysis has important applications for time-dependent crystallographic data, extracting significant information. Herein, a successful application of SVD analysis of time-resolved powder diffraction data over the course of an in-situ photodimerization reaction of anthracene derivatives is introduced. SVD revealed significant results in the case of 9-methylanthracene and 1-chloroanthracene. The results support the formation of the 9-methylanthracene stable dimer phase and suggest the existence of an excimer state. International Union of Crystallography 2014-04-02 /pmc/articles/PMC4333817/ /pubmed/24763645 http://dx.doi.org/10.1107/S1600577514004366 Text en © Ahmed F. Mabied et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Papers
Mabied, Ahmed F.
Nozawa, Shunsuke
Hoshino, Manabu
Tomita, Ayana
Sato, Tokushi
Adachi, Shin-ichi
Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title_full Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title_fullStr Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title_full_unstemmed Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title_short Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
title_sort application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction
topic Research Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333817/
https://www.ncbi.nlm.nih.gov/pubmed/24763645
http://dx.doi.org/10.1107/S1600577514004366
work_keys_str_mv AT mabiedahmedf applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction
AT nozawashunsuke applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction
AT hoshinomanabu applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction
AT tomitaayana applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction
AT satotokushi applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction
AT adachishinichi applicationofsingularvaluedecompositionanalysistotimedependentpowderdiffractiondataofaninsituphotodimerizationreaction

Ejemplares similares