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The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry
Biological nitrogen fixation is enabled by molybdenum-dependent nitrogenase enzymes, which effect the reduction of dinitrogen to ammonia using an Fe(7)MoS(9)C active site, referred to as the iron molybdenum cofactor or FeMoco. In this mini-review, we summarize the current understanding of the molecu...
Autores principales: | Bjornsson, Ragnar, Neese, Frank, Schrock, Richard R., Einsle, Oliver, DeBeer, Serena |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Berlin Heidelberg
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4334110/ https://www.ncbi.nlm.nih.gov/pubmed/25549604 http://dx.doi.org/10.1007/s00775-014-1230-6 |
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