Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners

[Image: see text] Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene ana...

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Autores principales: Wright, Nathan E., ElSohly, Adel M., Snyder, Scott A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4334237/
https://www.ncbi.nlm.nih.gov/pubmed/24987807
http://dx.doi.org/10.1021/ol501284s
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author Wright, Nathan E.
ElSohly, Adel M.
Snyder, Scott A.
author_facet Wright, Nathan E.
ElSohly, Adel M.
Snyder, Scott A.
author_sort Wright, Nathan E.
collection PubMed
description [Image: see text] Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A second triketone synthesis and computational studies indicate the parameters needed for success.
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spelling pubmed-43342372015-07-02 Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners Wright, Nathan E. ElSohly, Adel M. Snyder, Scott A. Org Lett [Image: see text] Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A second triketone synthesis and computational studies indicate the parameters needed for success. American Chemical Society 2014-07-02 2014-07-18 /pmc/articles/PMC4334237/ /pubmed/24987807 http://dx.doi.org/10.1021/ol501284s Text en Copyright © 2014 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Wright, Nathan E.
ElSohly, Adel M.
Snyder, Scott A.
Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title_full Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title_fullStr Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title_full_unstemmed Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title_short Syntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
title_sort syntheses of cyclotriveratrylene analogues and their long elusive triketone congeners
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4334237/
https://www.ncbi.nlm.nih.gov/pubmed/24987807
http://dx.doi.org/10.1021/ol501284s
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