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Effective beam method for element concentrations

There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At...

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Detalles Bibliográficos
Autores principales: Tolhurst, Thomas, Barbi, Mauricio, Tokaryk, Tim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344361/
https://www.ncbi.nlm.nih.gov/pubmed/25723941
http://dx.doi.org/10.1107/S1600577514026575
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author Tolhurst, Thomas
Barbi, Mauricio
Tokaryk, Tim
author_facet Tolhurst, Thomas
Barbi, Mauricio
Tokaryk, Tim
author_sort Tolhurst, Thomas
collection PubMed
description There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At the same time the incident radiation spectrum, necessary for some research, may not be known on a given beamline. A preliminary presentation of a method applicable to X-ray fluorescence spectrocopic analyses that overcomes the lack of information about the incident beam spectrum that addresses both of these concerns is given here. The method is equally applicable for other X-ray sources so long as local conditions are considered. It relies on replacing the polychromatic spectrum in a standard fundamental parameters analysis with a set of effective monochromatic photon beams. A beam is associated with each element and can be described by an analytical function allowing extension to elements not included in the necessary calibration measurement(s).
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spelling pubmed-43443612015-03-18 Effective beam method for element concentrations Tolhurst, Thomas Barbi, Mauricio Tokaryk, Tim J Synchrotron Radiat Research Papers There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At the same time the incident radiation spectrum, necessary for some research, may not be known on a given beamline. A preliminary presentation of a method applicable to X-ray fluorescence spectrocopic analyses that overcomes the lack of information about the incident beam spectrum that addresses both of these concerns is given here. The method is equally applicable for other X-ray sources so long as local conditions are considered. It relies on replacing the polychromatic spectrum in a standard fundamental parameters analysis with a set of effective monochromatic photon beams. A beam is associated with each element and can be described by an analytical function allowing extension to elements not included in the necessary calibration measurement(s). International Union of Crystallography 2015-01-29 /pmc/articles/PMC4344361/ /pubmed/25723941 http://dx.doi.org/10.1107/S1600577514026575 Text en © Thomas Tolhurst et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Papers
Tolhurst, Thomas
Barbi, Mauricio
Tokaryk, Tim
Effective beam method for element concentrations
title Effective beam method for element concentrations
title_full Effective beam method for element concentrations
title_fullStr Effective beam method for element concentrations
title_full_unstemmed Effective beam method for element concentrations
title_short Effective beam method for element concentrations
title_sort effective beam method for element concentrations
topic Research Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344361/
https://www.ncbi.nlm.nih.gov/pubmed/25723941
http://dx.doi.org/10.1107/S1600577514026575
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