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Effective beam method for element concentrations
There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344361/ https://www.ncbi.nlm.nih.gov/pubmed/25723941 http://dx.doi.org/10.1107/S1600577514026575 |
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author | Tolhurst, Thomas Barbi, Mauricio Tokaryk, Tim |
author_facet | Tolhurst, Thomas Barbi, Mauricio Tokaryk, Tim |
author_sort | Tolhurst, Thomas |
collection | PubMed |
description | There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At the same time the incident radiation spectrum, necessary for some research, may not be known on a given beamline. A preliminary presentation of a method applicable to X-ray fluorescence spectrocopic analyses that overcomes the lack of information about the incident beam spectrum that addresses both of these concerns is given here. The method is equally applicable for other X-ray sources so long as local conditions are considered. It relies on replacing the polychromatic spectrum in a standard fundamental parameters analysis with a set of effective monochromatic photon beams. A beam is associated with each element and can be described by an analytical function allowing extension to elements not included in the necessary calibration measurement(s). |
format | Online Article Text |
id | pubmed-4344361 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43443612015-03-18 Effective beam method for element concentrations Tolhurst, Thomas Barbi, Mauricio Tokaryk, Tim J Synchrotron Radiat Research Papers There is a great diversity of research being conducted at synchrotron facilities around the world and a diverse set of beamlines to accommodate this research. Time is a precious commodity at synchrotron facilities; therefore, methods that can maximize the time spent collecting data are of value. At the same time the incident radiation spectrum, necessary for some research, may not be known on a given beamline. A preliminary presentation of a method applicable to X-ray fluorescence spectrocopic analyses that overcomes the lack of information about the incident beam spectrum that addresses both of these concerns is given here. The method is equally applicable for other X-ray sources so long as local conditions are considered. It relies on replacing the polychromatic spectrum in a standard fundamental parameters analysis with a set of effective monochromatic photon beams. A beam is associated with each element and can be described by an analytical function allowing extension to elements not included in the necessary calibration measurement(s). International Union of Crystallography 2015-01-29 /pmc/articles/PMC4344361/ /pubmed/25723941 http://dx.doi.org/10.1107/S1600577514026575 Text en © Thomas Tolhurst et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Papers Tolhurst, Thomas Barbi, Mauricio Tokaryk, Tim Effective beam method for element concentrations |
title | Effective beam method for element concentrations |
title_full | Effective beam method for element concentrations |
title_fullStr | Effective beam method for element concentrations |
title_full_unstemmed | Effective beam method for element concentrations |
title_short | Effective beam method for element concentrations |
title_sort | effective beam method for element concentrations |
topic | Research Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344361/ https://www.ncbi.nlm.nih.gov/pubmed/25723941 http://dx.doi.org/10.1107/S1600577514026575 |
work_keys_str_mv | AT tolhurstthomas effectivebeammethodforelementconcentrations AT barbimauricio effectivebeammethodforelementconcentrations AT tokaryktim effectivebeammethodforelementconcentrations |