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Crystal structure of 1-{1-[2-(phenylselanyl)phenyl]-1H-1,2,3-triazol-4-yl}cyclohexan-1-ol
Two independent molecules, A and B, comprise the asymmetric unit of the title compound, C(20)H(21)N(3)OSe. While the benzene ring directly bound to the central triazole ring is inclined to the same extent in both molecules [dihedral angles = 40.41 (12) (molecule A) and 44.14 (12)° (B)], greater d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350684/ https://www.ncbi.nlm.nih.gov/pubmed/25844248 http://dx.doi.org/10.1107/S2056989015003242 |
Sumario: | Two independent molecules, A and B, comprise the asymmetric unit of the title compound, C(20)H(21)N(3)OSe. While the benzene ring directly bound to the central triazole ring is inclined to the same extent in both molecules [dihedral angles = 40.41 (12) (molecule A) and 44.14 (12)° (B)], greater differences are apparent in the dihedral angles between the Se-bound rings, i.e. 74.28 (12) (molecule A) and 89.91 (11)° (B). Close intramolecular Se⋯N interactions of 2.9311 (18) (molecule A) and 2.9482 (18) Å (B) are noted. In the crystal, supramolecular chains along the a axis are formed via O—H⋯N hydrogen bonding. These are connected into layers via C—H⋯O and C—H⋯N interactions; these stack along (01-1) without directional intermolecular interactions between them. |
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