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Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile

In the title compound C(22)H(18)BrN(3), the cyclo­pentane ring adopts an envelope conformation with the central methyl­ene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromo­benzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the c...

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Detalles Bibliográficos
Autores principales: Nagalakshmi, R. A., Suresh, J., Maharani, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350685/
https://www.ncbi.nlm.nih.gov/pubmed/25844192
http://dx.doi.org/10.1107/S2056989015002820
Descripción
Sumario:In the title compound C(22)H(18)BrN(3), the cyclo­pentane ring adopts an envelope conformation with the central methyl­ene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromo­benzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the crystal, inversion dimers linked by pairs of N—H⋯N(n) (n = nitrile) hydrogen bonds generate R (2) (2)(12) loops. These dimers are linked by weak π–π inter­actions [centroid–centroid distance = 3.7713 (14) Å] into a layered structure.