Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile

In the title compound C(22)H(18)BrN(3), the cyclo­pentane ring adopts an envelope conformation with the central methyl­ene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromo­benzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Nagalakshmi, R. A., Suresh, J., Maharani, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350685/
https://www.ncbi.nlm.nih.gov/pubmed/25844192
http://dx.doi.org/10.1107/S2056989015002820
_version_ 1782360217935151104
author Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Nagalakshmi, R. A.
collection PubMed
description In the title compound C(22)H(18)BrN(3), the cyclo­pentane ring adopts an envelope conformation with the central methyl­ene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromo­benzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the crystal, inversion dimers linked by pairs of N—H⋯N(n) (n = nitrile) hydrogen bonds generate R (2) (2)(12) loops. These dimers are linked by weak π–π inter­actions [centroid–centroid distance = 3.7713 (14) Å] into a layered structure.
format Online
Article
Text
id pubmed-4350685
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43506852015-04-03 Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr E Crystallogr Commun Research Communications In the title compound C(22)H(18)BrN(3), the cyclo­pentane ring adopts an envelope conformation with the central methyl­ene C atom as the flap. The dihedral angles between the central pyridine ring and the pendant benzyl and and bromo­benzene rings are 82.65 (1) and 47.23 (1)°, respectively. In the crystal, inversion dimers linked by pairs of N—H⋯N(n) (n = nitrile) hydrogen bonds generate R (2) (2)(12) loops. These dimers are linked by weak π–π inter­actions [centroid–centroid distance = 3.7713 (14) Å] into a layered structure. International Union of Crystallography 2015-02-21 /pmc/articles/PMC4350685/ /pubmed/25844192 http://dx.doi.org/10.1107/S2056989015002820 Text en © Nagalakshmi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_full Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_fullStr Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_full_unstemmed Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_short Crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_sort crystal structure of 2-benzyl­amino-4-(4-bromo­phen­yl)-6,7-di­hydro-5h-cyclo­penta­[b]pyridine-3-carbo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350685/
https://www.ncbi.nlm.nih.gov/pubmed/25844192
http://dx.doi.org/10.1107/S2056989015002820
work_keys_str_mv AT nagalakshmira crystalstructureof2benzylamino44bromophenyl67dihydro5hcyclopentabpyridine3carbonitrile
AT sureshj crystalstructureof2benzylamino44bromophenyl67dihydro5hcyclopentabpyridine3carbonitrile
AT maharanis crystalstructureof2benzylamino44bromophenyl67dihydro5hcyclopentabpyridine3carbonitrile
AT kumarrranjith crystalstructureof2benzylamino44bromophenyl67dihydro5hcyclopentabpyridine3carbonitrile
AT lakshmanplnilantha crystalstructureof2benzylamino44bromophenyl67dihydro5hcyclopentabpyridine3carbonitrile

Ejemplares similares