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Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350688/ https://www.ncbi.nlm.nih.gov/pubmed/25844203 http://dx.doi.org/10.1107/S2056989015001905 |
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author | Yousaf, Aqsa Tahir, Muhammad Nawaz Rauf, Abdul Awan, Shafique Ahmad Ahmad, Saeed |
author_facet | Yousaf, Aqsa Tahir, Muhammad Nawaz Rauf, Abdul Awan, Shafique Ahmad Ahmad, Saeed |
author_sort | Yousaf, Aqsa |
collection | PubMed |
description | The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and Ag—O bond lengths are 2.156 (5) and 2.162 (4) Å, respectively. The polymeric chains extend along the crystallographic a axis. Strong hydrogen bonds of the N—H⋯O and O—H⋯O types and additional C—H⋯O interactions connect these chains into a double-layer polymeric network in the ab plane. |
format | Online Article Text |
id | pubmed-4350688 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43506882015-04-03 Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N] Yousaf, Aqsa Tahir, Muhammad Nawaz Rauf, Abdul Awan, Shafique Ahmad Ahmad, Saeed Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and Ag—O bond lengths are 2.156 (5) and 2.162 (4) Å, respectively. The polymeric chains extend along the crystallographic a axis. Strong hydrogen bonds of the N—H⋯O and O—H⋯O types and additional C—H⋯O interactions connect these chains into a double-layer polymeric network in the ab plane. International Union of Crystallography 2015-02-04 /pmc/articles/PMC4350688/ /pubmed/25844203 http://dx.doi.org/10.1107/S2056989015001905 Text en © Yousaf et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Yousaf, Aqsa Tahir, Muhammad Nawaz Rauf, Abdul Awan, Shafique Ahmad Ahmad, Saeed Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N] |
title | Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2)
O:N] |
title_full | Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2)
O:N] |
title_fullStr | Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2)
O:N] |
title_full_unstemmed | Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2)
O:N] |
title_short | Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2)
O:N] |
title_sort | crystal structure of catena-poly[silver(i)-μ-l-tyrosinato-κ(2)
o:n] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350688/ https://www.ncbi.nlm.nih.gov/pubmed/25844203 http://dx.doi.org/10.1107/S2056989015001905 |
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