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Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]

The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and...

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Autores principales: Yousaf, Aqsa, Tahir, Muhammad Nawaz, Rauf, Abdul, Awan, Shafique Ahmad, Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350688/
https://www.ncbi.nlm.nih.gov/pubmed/25844203
http://dx.doi.org/10.1107/S2056989015001905
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author Yousaf, Aqsa
Tahir, Muhammad Nawaz
Rauf, Abdul
Awan, Shafique Ahmad
Ahmad, Saeed
author_facet Yousaf, Aqsa
Tahir, Muhammad Nawaz
Rauf, Abdul
Awan, Shafique Ahmad
Ahmad, Saeed
author_sort Yousaf, Aqsa
collection PubMed
description The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and Ag—O bond lengths are 2.156 (5) and 2.162 (4) Å, respectively. The polymeric chains extend along the crystallographic a axis. Strong hydrogen bonds of the N—H⋯O and O—H⋯O types and additional C—H⋯O inter­actions connect these chains into a double-layer polymeric network in the ab plane.
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spelling pubmed-43506882015-04-03 Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N] Yousaf, Aqsa Tahir, Muhammad Nawaz Rauf, Abdul Awan, Shafique Ahmad Ahmad, Saeed Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Ag(C(9)H(10)NO(3))](n), is a polymeric silver(I) complex of l-tyrosine. The Ag(I) atom is connected to N and O atoms of two different l-tyrosine ligands in an almost linear arrangement, with an N(i)—Ag—O1 bond angle of 173.4 (2)° [symmetry code: (i) x + 1, y, z]. The Ag—N(i) and Ag—O bond lengths are 2.156 (5) and 2.162 (4) Å, respectively. The polymeric chains extend along the crystallographic a axis. Strong hydrogen bonds of the N—H⋯O and O—H⋯O types and additional C—H⋯O inter­actions connect these chains into a double-layer polymeric network in the ab plane. International Union of Crystallography 2015-02-04 /pmc/articles/PMC4350688/ /pubmed/25844203 http://dx.doi.org/10.1107/S2056989015001905 Text en © Yousaf et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yousaf, Aqsa
Tahir, Muhammad Nawaz
Rauf, Abdul
Awan, Shafique Ahmad
Ahmad, Saeed
Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title_full Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title_fullStr Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title_full_unstemmed Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title_short Crystal structure of catena-poly[silver(I)-μ-l-tyrosinato-κ(2) O:N]
title_sort crystal structure of catena-poly[silver(i)-μ-l-tyrosinato-κ(2) o:n]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350688/
https://www.ncbi.nlm.nih.gov/pubmed/25844203
http://dx.doi.org/10.1107/S2056989015001905
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