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Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate

In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl gr...

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Autores principales: Davaasuren, Bambar, Padhy, Harihara, Rothenberger, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350693/
https://www.ncbi.nlm.nih.gov/pubmed/25844213
http://dx.doi.org/10.1107/S2056989015003473
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author Davaasuren, Bambar
Padhy, Harihara
Rothenberger, Alexander
author_facet Davaasuren, Bambar
Padhy, Harihara
Rothenberger, Alexander
author_sort Davaasuren, Bambar
collection PubMed
description In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol­ecules are stacked in rows parallel to [001], with the aceto­nitrile solvent mol­ecules situated between the rows. An extensive network of intra- and inter­molecular C—H⋯Cl inter­actions is present, stabilizing the three-dimensional structure.
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spelling pubmed-43506932015-04-03 Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate Davaasuren, Bambar Padhy, Harihara Rothenberger, Alexander Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol­ecules are stacked in rows parallel to [001], with the aceto­nitrile solvent mol­ecules situated between the rows. An extensive network of intra- and inter­molecular C—H⋯Cl inter­actions is present, stabilizing the three-dimensional structure. International Union of Crystallography 2015-02-25 /pmc/articles/PMC4350693/ /pubmed/25844213 http://dx.doi.org/10.1107/S2056989015003473 Text en © Davaasuren et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Davaasuren, Bambar
Padhy, Harihara
Rothenberger, Alexander
Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title_full Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title_fullStr Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title_full_unstemmed Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title_short Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) aceto­nitrile disolvate
title_sort crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)iridium(iii) aceto­nitrile disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350693/
https://www.ncbi.nlm.nih.gov/pubmed/25844213
http://dx.doi.org/10.1107/S2056989015003473
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