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Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) acetonitrile disolvate
In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octahedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl gr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350693/ https://www.ncbi.nlm.nih.gov/pubmed/25844213 http://dx.doi.org/10.1107/S2056989015003473 |
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author | Davaasuren, Bambar Padhy, Harihara Rothenberger, Alexander |
author_facet | Davaasuren, Bambar Padhy, Harihara Rothenberger, Alexander |
author_sort | Davaasuren, Bambar |
collection | PubMed |
description | In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octahedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, molecules are stacked in rows parallel to [001], with the acetonitrile solvent molecules situated between the rows. An extensive network of intra- and intermolecular C—H⋯Cl interactions is present, stabilizing the three-dimensional structure. |
format | Online Article Text |
id | pubmed-4350693 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43506932015-04-03 Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) acetonitrile disolvate Davaasuren, Bambar Padhy, Harihara Rothenberger, Alexander Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [FeIr(C(5)H(5))(C(20)H(14)N(3))Cl(3)]·2CH(3)CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octahedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, molecules are stacked in rows parallel to [001], with the acetonitrile solvent molecules situated between the rows. An extensive network of intra- and intermolecular C—H⋯Cl interactions is present, stabilizing the three-dimensional structure. International Union of Crystallography 2015-02-25 /pmc/articles/PMC4350693/ /pubmed/25844213 http://dx.doi.org/10.1107/S2056989015003473 Text en © Davaasuren et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Davaasuren, Bambar Padhy, Harihara Rothenberger, Alexander Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iridium(III) acetonitrile disolvate |
title | Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)iridium(III) acetonitrile disolvate |
title_full | Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)iridium(III) acetonitrile disolvate |
title_fullStr | Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)iridium(III) acetonitrile disolvate |
title_full_unstemmed | Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)iridium(III) acetonitrile disolvate |
title_short | Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)iridium(III) acetonitrile disolvate |
title_sort | crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)iridium(iii) acetonitrile disolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350693/ https://www.ncbi.nlm.nih.gov/pubmed/25844213 http://dx.doi.org/10.1107/S2056989015003473 |
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