Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate

The title compound, [Ir(η(5)-C(5)Me(5))Cl(C(18)H(14)ClN(3))]B(C(6)H(5))(4), is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinyl­idene­pyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinyl­idene groups forming a five-membered metallacycle. A...

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Autores principales: Devika, Neelakandan, Raja, Nandhagopal, Ananthalakshmi, Subbiah, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350695/
https://www.ncbi.nlm.nih.gov/pubmed/25844211
http://dx.doi.org/10.1107/S2056989015003023
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author Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
author_facet Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
author_sort Devika, Neelakandan
collection PubMed
description The title compound, [Ir(η(5)-C(5)Me(5))Cl(C(18)H(14)ClN(3))]B(C(6)H(5))(4), is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinyl­idene­pyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinyl­idene groups forming a five-membered metallacycle. An intra­molecular C—H⋯Cl hydrogen bond is observed. In the crystal, centrosymmetrically-related cations are connected by C—Cl⋯π inter­actions, forming a dimeric structure. The crystal packing is further stabilized by weak inter­ionic C—H⋯π inter­actions.
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spelling pubmed-43506952015-04-03 Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate Devika, Neelakandan Raja, Nandhagopal Ananthalakshmi, Subbiah Therrien, Bruno Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Ir(η(5)-C(5)Me(5))Cl(C(18)H(14)ClN(3))]B(C(6)H(5))(4), is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinyl­idene­pyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinyl­idene groups forming a five-membered metallacycle. An intra­molecular C—H⋯Cl hydrogen bond is observed. In the crystal, centrosymmetrically-related cations are connected by C—Cl⋯π inter­actions, forming a dimeric structure. The crystal packing is further stabilized by weak inter­ionic C—H⋯π inter­actions. International Union of Crystallography 2015-02-18 /pmc/articles/PMC4350695/ /pubmed/25844211 http://dx.doi.org/10.1107/S2056989015003023 Text en © Devika et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title_full Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title_fullStr Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title_full_unstemmed Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title_short Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate
title_sort crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κn (1)](phen­yl)meth­yl}pyridine-κn)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(iii) tetra­phenyl­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350695/
https://www.ncbi.nlm.nih.gov/pubmed/25844211
http://dx.doi.org/10.1107/S2056989015003023
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