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Crystal structure of chlorido(2-{[2-(4-chlorophenyl)hydrazin-1-ylidene-κN (1)](phenyl)methyl}pyridine-κN)(η(5)-pentamethylcyclopentadienyl)iridium(III) tetraphenylborate

The title compound, [Ir(η(5)-C(5)Me(5))Cl(C(18)H(14)ClN(3))]B(C(6)H(5))(4), is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinylidenepyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinylidene groups forming a five-membered metallacycle. A...

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Detalles Bibliográficos
Autores principales:	Devika, Neelakandan, Raja, Nandhagopal, Ananthalakshmi, Subbiah, Therrien, Bruno
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2015
Materias:	Data Reports
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350695/ https://www.ncbi.nlm.nih.gov/pubmed/25844211 http://dx.doi.org/10.1107/S2056989015003023

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