Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)

The mol­ecule of the title compound, [Co(C(8)H(6)NO(4))(2)(H(2)O)(4)], is centrosymmetric. It is a cobalt(II) complex, bearing two (2-nitro­phen­yl)acetate and four aqua ligands. The coordination around the Co(II) atom is distorted octa­hedral, defined by four O atoms of water mol­ecules in the equa...

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Autores principales: Danish, Muhammad, Tahir, Muhammad Nawaz, Iftikhar, Sana, Raza, Muhammad Asam, Ashfaq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350698/
https://www.ncbi.nlm.nih.gov/pubmed/25844208
http://dx.doi.org/10.1107/S2056989015002467
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author Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
author_facet Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
author_sort Danish, Muhammad
collection PubMed
description The mol­ecule of the title compound, [Co(C(8)H(6)NO(4))(2)(H(2)O)(4)], is centrosymmetric. It is a cobalt(II) complex, bearing two (2-nitro­phen­yl)acetate and four aqua ligands. The coordination around the Co(II) atom is distorted octa­hedral, defined by four O atoms of water mol­ecules in the equatorial plane and by two carboxyl­ate O atoms at axial positions. The dihedral angles between the benzene ring and the acetate and nitro groups are 61.90 (10) and 19.21 (11)°, respectively. The water mol­ecules form O—H⋯O hydrogen bonds with the nitro and carboxyl­ate groups, leading to a layered structural arrangement parallel to (001).
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spelling pubmed-43506982015-04-03 Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II) Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports The mol­ecule of the title compound, [Co(C(8)H(6)NO(4))(2)(H(2)O)(4)], is centrosymmetric. It is a cobalt(II) complex, bearing two (2-nitro­phen­yl)acetate and four aqua ligands. The coordination around the Co(II) atom is distorted octa­hedral, defined by four O atoms of water mol­ecules in the equatorial plane and by two carboxyl­ate O atoms at axial positions. The dihedral angles between the benzene ring and the acetate and nitro groups are 61.90 (10) and 19.21 (11)°, respectively. The water mol­ecules form O—H⋯O hydrogen bonds with the nitro and carboxyl­ate groups, leading to a layered structural arrangement parallel to (001). International Union of Crystallography 2015-02-11 /pmc/articles/PMC4350698/ /pubmed/25844208 http://dx.doi.org/10.1107/S2056989015002467 Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title_full Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title_fullStr Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title_full_unstemmed Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title_short Tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κO]cobalt(II)
title_sort tetra­aqua­bis­[2-(2-nitro­phen­yl)acetato-κo]cobalt(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350698/
https://www.ncbi.nlm.nih.gov/pubmed/25844208
http://dx.doi.org/10.1107/S2056989015002467
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