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Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium
The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octahedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ide ligands, through imidazol...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350700/ https://www.ncbi.nlm.nih.gov/pubmed/25844199 http://dx.doi.org/10.1107/S2056989015003758 |
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author | Shi, Yabin Lou, Benyong |
author_facet | Shi, Yabin Lou, Benyong |
author_sort | Shi, Yabin |
collection | PubMed |
description | The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octahedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ide ligands, through imidazole ring N atoms, in the axial sites. An intramolecular O—H⋯O hydrogen bond forms an S(7) graph-set motif. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link complex molecules forming a three-dimensional network incorporating R (4) (2)(8) and R (2) (2)(18) graph-set motifs. |
format | Online Article Text |
id | pubmed-4350700 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43507002015-04-03 Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium Shi, Yabin Lou, Benyong Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octahedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ide ligands, through imidazole ring N atoms, in the axial sites. An intramolecular O—H⋯O hydrogen bond forms an S(7) graph-set motif. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link complex molecules forming a three-dimensional network incorporating R (4) (2)(8) and R (2) (2)(18) graph-set motifs. International Union of Crystallography 2015-02-28 /pmc/articles/PMC4350700/ /pubmed/25844199 http://dx.doi.org/10.1107/S2056989015003758 Text en © Shi and Lou 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shi, Yabin Lou, Benyong Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title | Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title_full | Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title_fullStr | Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title_full_unstemmed | Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title_short | Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium |
title_sort | crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1h-purin-9-ido)magnesium |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350700/ https://www.ncbi.nlm.nih.gov/pubmed/25844199 http://dx.doi.org/10.1107/S2056989015003758 |
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