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Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium

The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octa­hedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ide ligands, through imidazol...

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Detalles Bibliográficos
Autores principales: Shi, Yabin, Lou, Benyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350700/
https://www.ncbi.nlm.nih.gov/pubmed/25844199
http://dx.doi.org/10.1107/S2056989015003758
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author Shi, Yabin
Lou, Benyong
author_facet Shi, Yabin
Lou, Benyong
author_sort Shi, Yabin
collection PubMed
description The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octa­hedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ide ligands, through imidazole ring N atoms, in the axial sites. An intra­molecular O—H⋯O hydrogen bond forms an S(7) graph-set motif. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link complex mol­ecules forming a three-dimensional network incorporating R (4) (2)(8) and R (2) (2)(18) graph-set motifs.
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spelling pubmed-43507002015-04-03 Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium Shi, Yabin Lou, Benyong Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Mg(C(7)H(7)N(4)O(2))(2)(H(2)O)(4)], lies across an inversion centre and the Mg(II) atom is coordinated in a slightly distorted octa­hedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ide ligands, through imidazole ring N atoms, in the axial sites. An intra­molecular O—H⋯O hydrogen bond forms an S(7) graph-set motif. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link complex mol­ecules forming a three-dimensional network incorporating R (4) (2)(8) and R (2) (2)(18) graph-set motifs. International Union of Crystallography 2015-02-28 /pmc/articles/PMC4350700/ /pubmed/25844199 http://dx.doi.org/10.1107/S2056989015003758 Text en © Shi and Lou 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shi, Yabin
Lou, Benyong
Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title_full Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title_fullStr Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title_full_unstemmed Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title_short Crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1H-purin-9-ido)magnesium
title_sort crystal structure of tetra­aquabis(1,3-dimethyl-2,6-dioxo-3,7-di­hydro-1h-purin-9-ido)magnesium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350700/
https://www.ncbi.nlm.nih.gov/pubmed/25844199
http://dx.doi.org/10.1107/S2056989015003758
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