Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate

The title compound, C(22)H(19)NO(4)S, has an almost planar geometry supported by intra­molecular N—H⋯O and C—H⋯O hydrogen bonds. The thio­phene ring is inclined to the azulene ring by 4.85 (16)°, while the eth­oxy­carbonyl groups are inclined to the azulene ring by 7.0 (2) and 5.7 (2)°. In the cryst...

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Detalles Bibliográficos
Autores principales: Förster, Sebastian, Seichter, Wilhelm, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350707/
https://www.ncbi.nlm.nih.gov/pubmed/25844254
http://dx.doi.org/10.1107/S2056989015003898
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author Förster, Sebastian
Seichter, Wilhelm
Weber, Edwin
author_facet Förster, Sebastian
Seichter, Wilhelm
Weber, Edwin
author_sort Förster, Sebastian
collection PubMed
description The title compound, C(22)H(19)NO(4)S, has an almost planar geometry supported by intra­molecular N—H⋯O and C—H⋯O hydrogen bonds. The thio­phene ring is inclined to the azulene ring by 4.85 (16)°, while the eth­oxy­carbonyl groups are inclined to the azulene ring by 7.0 (2) and 5.7 (2)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked via C—H⋯π inter­actions, forming sheets parallel to (10-1).
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spelling pubmed-43507072015-04-03 Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate Förster, Sebastian Seichter, Wilhelm Weber, Edwin Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(22)H(19)NO(4)S, has an almost planar geometry supported by intra­molecular N—H⋯O and C—H⋯O hydrogen bonds. The thio­phene ring is inclined to the azulene ring by 4.85 (16)°, while the eth­oxy­carbonyl groups are inclined to the azulene ring by 7.0 (2) and 5.7 (2)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked via C—H⋯π inter­actions, forming sheets parallel to (10-1). International Union of Crystallography 2015-02-28 /pmc/articles/PMC4350707/ /pubmed/25844254 http://dx.doi.org/10.1107/S2056989015003898 Text en © Förster et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Förster, Sebastian
Seichter, Wilhelm
Weber, Edwin
Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title_full Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title_fullStr Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title_full_unstemmed Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title_short Crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
title_sort crystal structure of diethyl 2-amino-6-[(thio­phen-3-yl)ethyn­yl]azulene-1,3-di­carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350707/
https://www.ncbi.nlm.nih.gov/pubmed/25844254
http://dx.doi.org/10.1107/S2056989015003898
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