Cargando…
Crystal structure of bis(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
The title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(2)]·2C(4)H(6)N(2), is a six-coordinate Fe(II)–porphyrinate complex with the metal located on a center of inversion and coordinated by two axial 1-methylimidazole ligands; the complex crystallizes as a 1-methylimidazole disolvate. The 1-methyli...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350711/ https://www.ncbi.nlm.nih.gov/pubmed/25844207 http://dx.doi.org/10.1107/S2056989015002364 |
| Sumario: | The title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(2)]·2C(4)H(6)N(2), is a six-coordinate Fe(II)–porphyrinate complex with the metal located on a center of inversion and coordinated by two axial 1-methylimidazole ligands; the complex crystallizes as a 1-methylimidazole disolvate. The 1-methylimidazole group bonded to the Fe(II) atom [occupancy ratio 0.789 (4):0.211 (4)] and the unbound 1-methylimidazole molecule [0.519 (4):0.481 (4)] were disordered. The average Fe—N(porphyrinate) bond length is 1.998 (3) Å and the axial Fe—N(imidazole) bond length is 1.9970 (12) Å. In the crystal, molecules are linked into a three-molecule aggregate by two weak C—H⋯N interactions. |
|---|