Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)

The title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(2)]·2C(4)H(6)N(2), is a six-coordinate Fe(II)–porphyrinate complex with the metal located on a center of inversion and coordinated by two axial 1-methyl­imidazole ligands; the complex crystallizes as a 1-methyl­imidazole disolvate. The 1-methyl­i...

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Detalles Bibliográficos
Autores principales: Guan, Ye, Powell, Douglas R., Richter-Addo, George B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350711/
https://www.ncbi.nlm.nih.gov/pubmed/25844207
http://dx.doi.org/10.1107/S2056989015002364
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author Guan, Ye
Powell, Douglas R.
Richter-Addo, George B.
author_facet Guan, Ye
Powell, Douglas R.
Richter-Addo, George B.
author_sort Guan, Ye
collection PubMed
description The title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(2)]·2C(4)H(6)N(2), is a six-coordinate Fe(II)–porphyrinate complex with the metal located on a center of inversion and coordinated by two axial 1-methyl­imidazole ligands; the complex crystallizes as a 1-methyl­imidazole disolvate. The 1-methyl­imidazole group bonded to the Fe(II) atom [occupancy ratio 0.789 (4):0.211 (4)] and the unbound 1-methyl­imidazole mol­ecule [0.519 (4):0.481 (4)] were disordered. The average Fe—N(porphyrinate) bond length is 1.998 (3) Å and the axial Fe—N(imidazole) bond length is 1.9970 (12) Å. In the crystal, mol­ecules are linked into a three-mol­ecule aggregate by two weak C—H⋯N inter­actions.
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spelling pubmed-43507112015-04-03 Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2) Guan, Ye Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(2)]·2C(4)H(6)N(2), is a six-coordinate Fe(II)–porphyrinate complex with the metal located on a center of inversion and coordinated by two axial 1-methyl­imidazole ligands; the complex crystallizes as a 1-methyl­imidazole disolvate. The 1-methyl­imidazole group bonded to the Fe(II) atom [occupancy ratio 0.789 (4):0.211 (4)] and the unbound 1-methyl­imidazole mol­ecule [0.519 (4):0.481 (4)] were disordered. The average Fe—N(porphyrinate) bond length is 1.998 (3) Å and the axial Fe—N(imidazole) bond length is 1.9970 (12) Å. In the crystal, mol­ecules are linked into a three-mol­ecule aggregate by two weak C—H⋯N inter­actions. International Union of Crystallography 2015-02-11 /pmc/articles/PMC4350711/ /pubmed/25844207 http://dx.doi.org/10.1107/S2056989015002364 Text en © Guan et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Guan, Ye
Powell, Douglas R.
Richter-Addo, George B.
Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title_full Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title_fullStr Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title_full_unstemmed Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title_short Crystal structure of bis­(1-methyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II)–1-methyl-1H-imidazole (1/2)
title_sort crystal structure of bis­(1-methyl-1h-imidazole-κn (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)iron(ii)–1-methyl-1h-imidazole (1/2)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350711/
https://www.ncbi.nlm.nih.gov/pubmed/25844207
http://dx.doi.org/10.1107/S2056989015002364
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