Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene

In the title compound, C(12)H(9)BrSe, the Se atom exhibits a bent geometry, with a C—Se—C bond angle of 99.19 (6)°. The ortho Se and Br atoms are slightly displaced from opposite faces of the mean plane of the benzene ring [by 0.129 (2) and 0.052 (2) Å, respectively]. The planes of the benzene and p...

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Detalles Bibliográficos
Autores principales: Charette, Bronte J., Ritch, Jamie S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350714/
https://www.ncbi.nlm.nih.gov/pubmed/25844201
http://dx.doi.org/10.1107/S205698901500345X
Descripción
Sumario:In the title compound, C(12)H(9)BrSe, the Se atom exhibits a bent geometry, with a C—Se—C bond angle of 99.19 (6)°. The ortho Se and Br atoms are slightly displaced from opposite faces of the mean plane of the benzene ring [by 0.129 (2) and 0.052 (2) Å, respectively]. The planes of the benzene and phenyl rings form a dihedral angle of 72.69 (5)°. In the crystal, π-stacking inter­actions between inversion-related phenyl rings are observed, with a centroid–centroid distance of 3.630 (1) Å.

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