Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene

In the title compound, C(12)H(9)BrSe, the Se atom exhibits a bent geometry, with a C—Se—C bond angle of 99.19 (6)°. The ortho Se and Br atoms are slightly displaced from opposite faces of the mean plane of the benzene ring [by 0.129 (2) and 0.052 (2) Å, respectively]. The planes of the benzene and p...

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Autores principales: Charette, Bronte J., Ritch, Jamie S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350714/
https://www.ncbi.nlm.nih.gov/pubmed/25844201
http://dx.doi.org/10.1107/S205698901500345X
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author Charette, Bronte J.
Ritch, Jamie S.
author_facet Charette, Bronte J.
Ritch, Jamie S.
author_sort Charette, Bronte J.
collection PubMed
description In the title compound, C(12)H(9)BrSe, the Se atom exhibits a bent geometry, with a C—Se—C bond angle of 99.19 (6)°. The ortho Se and Br atoms are slightly displaced from opposite faces of the mean plane of the benzene ring [by 0.129 (2) and 0.052 (2) Å, respectively]. The planes of the benzene and phenyl rings form a dihedral angle of 72.69 (5)°. In the crystal, π-stacking inter­actions between inversion-related phenyl rings are observed, with a centroid–centroid distance of 3.630 (1) Å.
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spelling pubmed-43507142015-04-03 Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene Charette, Bronte J. Ritch, Jamie S. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(12)H(9)BrSe, the Se atom exhibits a bent geometry, with a C—Se—C bond angle of 99.19 (6)°. The ortho Se and Br atoms are slightly displaced from opposite faces of the mean plane of the benzene ring [by 0.129 (2) and 0.052 (2) Å, respectively]. The planes of the benzene and phenyl rings form a dihedral angle of 72.69 (5)°. In the crystal, π-stacking inter­actions between inversion-related phenyl rings are observed, with a centroid–centroid distance of 3.630 (1) Å. International Union of Crystallography 2015-02-28 /pmc/articles/PMC4350714/ /pubmed/25844201 http://dx.doi.org/10.1107/S205698901500345X Text en © Charette and Ritch 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Charette, Bronte J.
Ritch, Jamie S.
Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title_full Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title_fullStr Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title_full_unstemmed Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title_short Crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
title_sort crystal structure of 1-bromo-2-(phenyl­selen­yl)benzene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350714/
https://www.ncbi.nlm.nih.gov/pubmed/25844201
http://dx.doi.org/10.1107/S205698901500345X
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