Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate

In the title mol­ecular salt, C(9)H(17)N(2) (+)·C(2)H(12)B(9) (−), the carborane cage has a bridging B—H—B bond on the open B(3)C(2) face. The butyl side chain of the cation adopts an extended conformation [C—C—C—C = 179.6 (1)°]. In the crystal, the imidazolium ring is almost coplanar with the open...

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Autores principales: Klemes, M. J., Soderstrom, L., Hunting, J. L., Larsen, A. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350724/
https://www.ncbi.nlm.nih.gov/pubmed/25844238
http://dx.doi.org/10.1107/S2056989015002765
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author Klemes, M. J.
Soderstrom, L.
Hunting, J. L.
Larsen, A. S.
author_facet Klemes, M. J.
Soderstrom, L.
Hunting, J. L.
Larsen, A. S.
author_sort Klemes, M. J.
collection PubMed
description In the title mol­ecular salt, C(9)H(17)N(2) (+)·C(2)H(12)B(9) (−), the carborane cage has a bridging B—H—B bond on the open B(3)C(2) face. The butyl side chain of the cation adopts an extended conformation [C—C—C—C = 179.6 (1)°]. In the crystal, the imidazolium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions.
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spelling pubmed-43507242015-04-03 Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate Klemes, M. J. Soderstrom, L. Hunting, J. L. Larsen, A. S. Acta Crystallogr E Crystallogr Commun Data Reports In the title mol­ecular salt, C(9)H(17)N(2) (+)·C(2)H(12)B(9) (−), the carborane cage has a bridging B—H—B bond on the open B(3)C(2) face. The butyl side chain of the cation adopts an extended conformation [C—C—C—C = 179.6 (1)°]. In the crystal, the imidazolium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions. International Union of Crystallography 2015-02-13 /pmc/articles/PMC4350724/ /pubmed/25844238 http://dx.doi.org/10.1107/S2056989015002765 Text en © Klemes et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Klemes, M. J.
Soderstrom, L.
Hunting, J. L.
Larsen, A. S.
Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title_full Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title_fullStr Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title_full_unstemmed Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title_short Crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
title_sort crystal structure of 1-butyl-2,3-di­methyl­imidazolium dicarba-7,8-nido-undeca­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350724/
https://www.ncbi.nlm.nih.gov/pubmed/25844238
http://dx.doi.org/10.1107/S2056989015002765
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