Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)

Potassium rubidium cobalt(II)/titanium(IV) tris­(orthophosphate), Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3), has been obtained using a high-temperature crystallization method. The obtained compound has a langbeinite-type structure. The three-dimensional framework is built up from mixed-occupied...

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Autores principales: Strutynska, Nataliia Yu., Bondarenko, Marina A., Ogorodnyk, Ivan V., Baumer, Vyacheslav N., Slobodyanik, Nikolay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350725/
https://www.ncbi.nlm.nih.gov/pubmed/25844179
http://dx.doi.org/10.1107/S2056989015001826
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author Strutynska, Nataliia Yu.
Bondarenko, Marina A.
Ogorodnyk, Ivan V.
Baumer, Vyacheslav N.
Slobodyanik, Nikolay S.
author_facet Strutynska, Nataliia Yu.
Bondarenko, Marina A.
Ogorodnyk, Ivan V.
Baumer, Vyacheslav N.
Slobodyanik, Nikolay S.
author_sort Strutynska, Nataliia Yu.
collection PubMed
description Potassium rubidium cobalt(II)/titanium(IV) tris­(orthophosphate), Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3), has been obtained using a high-temperature crystallization method. The obtained compound has a langbeinite-type structure. The three-dimensional framework is built up from mixed-occupied (Co/Ti(IV))O(6) octa­hedra (point group symmetry .3.) and PO(4) tetra­hedra. The K(+) and Rb(+) cations are statistically distributed over two distinct sites (both with site symmetry .3.) in the large cavities of the framework. They are surrounded by 12 O atoms.
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spelling pubmed-43507252015-04-03 Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3) Strutynska, Nataliia Yu. Bondarenko, Marina A. Ogorodnyk, Ivan V. Baumer, Vyacheslav N. Slobodyanik, Nikolay S. Acta Crystallogr E Crystallogr Commun Research Communications Potassium rubidium cobalt(II)/titanium(IV) tris­(orthophosphate), Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3), has been obtained using a high-temperature crystallization method. The obtained compound has a langbeinite-type structure. The three-dimensional framework is built up from mixed-occupied (Co/Ti(IV))O(6) octa­hedra (point group symmetry .3.) and PO(4) tetra­hedra. The K(+) and Rb(+) cations are statistically distributed over two distinct sites (both with site symmetry .3.) in the large cavities of the framework. They are surrounded by 12 O atoms. International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350725/ /pubmed/25844179 http://dx.doi.org/10.1107/S2056989015001826 Text en © Strutynska et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Strutynska, Nataliia Yu.
Bondarenko, Marina A.
Ogorodnyk, Ivan V.
Baumer, Vyacheslav N.
Slobodyanik, Nikolay S.
Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title_full Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title_fullStr Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title_full_unstemmed Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title_short Crystal structure of langbeinite-related Rb(0.743)K(0.845)Co(0.293)Ti(1.707)(PO(4))(3)
title_sort crystal structure of langbeinite-related rb(0.743)k(0.845)co(0.293)ti(1.707)(po(4))(3)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350725/
https://www.ncbi.nlm.nih.gov/pubmed/25844179
http://dx.doi.org/10.1107/S2056989015001826
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