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Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]

In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxyl­ate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and t...

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Autores principales: Danish, Muhammad, Tahir, Muhammad Nawaz, Iftikhar, Sana, Raza, Muhammad Asam, Ashfaq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350728/
https://www.ncbi.nlm.nih.gov/pubmed/25844204
http://dx.doi.org/10.1107/S205698901500198X
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author Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
author_facet Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
author_sort Danish, Muhammad
collection PubMed
description In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxyl­ate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2(1) screw axis. A weak π–π inter­action exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.
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spelling pubmed-43507282015-04-03 Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′] Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxyl­ate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2(1) screw axis. A weak π–π inter­action exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å. International Union of Crystallography 2015-02-04 /pmc/articles/PMC4350728/ /pubmed/25844204 http://dx.doi.org/10.1107/S205698901500198X Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Raza, Muhammad Asam
Ashfaq, Muhammad
Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title_full Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title_fullStr Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title_full_unstemmed Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title_short Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) O:O′]
title_sort crystal structure of catena-poly[[tri­methyl­tin(iv)]-μ-2-(2-nitro­phen­yl)acetato-κ(2) o:o′]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350728/
https://www.ncbi.nlm.nih.gov/pubmed/25844204
http://dx.doi.org/10.1107/S205698901500198X
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