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Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2) O:O′]
In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350728/ https://www.ncbi.nlm.nih.gov/pubmed/25844204 http://dx.doi.org/10.1107/S205698901500198X |
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author | Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad |
author_facet | Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad |
author_sort | Danish, Muhammad |
collection | PubMed |
description | In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2(1) screw axis. A weak π–π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å. |
format | Online Article Text |
id | pubmed-4350728 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43507282015-04-03 Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2) O:O′] Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title one-dimensional coordination polymer, [Sn(CH(3))(3)(C(8)H(6)NO(4))](n), the Sn(IV) atom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC(3)O(2) trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 2(1) screw axis. A weak π–π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å. International Union of Crystallography 2015-02-04 /pmc/articles/PMC4350728/ /pubmed/25844204 http://dx.doi.org/10.1107/S205698901500198X Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Raza, Muhammad Asam Ashfaq, Muhammad Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2) O:O′] |
title | Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2)
O:O′] |
title_full | Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2)
O:O′] |
title_fullStr | Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2)
O:O′] |
title_full_unstemmed | Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2)
O:O′] |
title_short | Crystal structure of catena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ(2)
O:O′] |
title_sort | crystal structure of catena-poly[[trimethyltin(iv)]-μ-2-(2-nitrophenyl)acetato-κ(2)
o:o′] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350728/ https://www.ncbi.nlm.nih.gov/pubmed/25844204 http://dx.doi.org/10.1107/S205698901500198X |
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