Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one

In the title compound, C(23)H(26)ClNO(2), the piperidin-4-one ring adopts a distorted boat conformation. The two p-tolyl rings are nearly normal to each other, making a dihedral angle of 83.33 (10)°. They are inclined to the mean plane of the piperidine ring by 73.2 (1) and 87.22 (9)°. In the crysta...

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Detalles Bibliográficos
Autores principales: Jothivel, S., Kotoky, Jibon, Kabilan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350729/
https://www.ncbi.nlm.nih.gov/pubmed/25844233
http://dx.doi.org/10.1107/S2056989015002613
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author Jothivel, S.
Kotoky, Jibon
Kabilan, S.
author_facet Jothivel, S.
Kotoky, Jibon
Kabilan, S.
author_sort Jothivel, S.
collection PubMed
description In the title compound, C(23)H(26)ClNO(2), the piperidin-4-one ring adopts a distorted boat conformation. The two p-tolyl rings are nearly normal to each other, making a dihedral angle of 83.33 (10)°. They are inclined to the mean plane of the piperidine ring by 73.2 (1) and 87.22 (9)°. In the crystal, there are no significant inter­molecular inter­actions present.
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spelling pubmed-43507292015-04-03 Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one Jothivel, S. Kotoky, Jibon Kabilan, S. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(23)H(26)ClNO(2), the piperidin-4-one ring adopts a distorted boat conformation. The two p-tolyl rings are nearly normal to each other, making a dihedral angle of 83.33 (10)°. They are inclined to the mean plane of the piperidine ring by 73.2 (1) and 87.22 (9)°. In the crystal, there are no significant inter­molecular inter­actions present. International Union of Crystallography 2015-02-13 /pmc/articles/PMC4350729/ /pubmed/25844233 http://dx.doi.org/10.1107/S2056989015002613 Text en © Jothivel et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Jothivel, S.
Kotoky, Jibon
Kabilan, S.
Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title_full Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title_fullStr Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title_full_unstemmed Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title_short Crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
title_sort crystal structure of 1-(2-chloro­acet­yl)-3,3-dimethyl-2,6-di-p-tolyl­piperidin-4-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350729/
https://www.ncbi.nlm.nih.gov/pubmed/25844233
http://dx.doi.org/10.1107/S2056989015002613
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