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Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione

In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the di­hydro­furan and 3,4-di­hydro­quinoline ring systems is 70.65 (9)°. The di­hydro­furan ring adopts an envelope conformation with the C atom adjacent to the methyl­ene C atom of the pyrrolidine ring as the...

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Autores principales: Savithri, M. P., Suresh, M., Raghunathan, R., Raja, R., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350735/
https://www.ncbi.nlm.nih.gov/pubmed/25844221
http://dx.doi.org/10.1107/S2056989015002017
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author Savithri, M. P.
Suresh, M.
Raghunathan, R.
Raja, R.
SubbiahPandi, A.
author_facet Savithri, M. P.
Suresh, M.
Raghunathan, R.
Raja, R.
SubbiahPandi, A.
author_sort Savithri, M. P.
collection PubMed
description In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the di­hydro­furan and 3,4-di­hydro­quinoline ring systems is 70.65 (9)°. The di­hydro­furan ring adopts an envelope conformation with the C atom adjacent to the methyl­ene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetra­substituted) bond. In the crystal, mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming ribbons enclosing R (2) (2)(12) ring motifs lying in a plane parallel to (01-1).
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spelling pubmed-43507352015-04-03 Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the di­hydro­furan and 3,4-di­hydro­quinoline ring systems is 70.65 (9)°. The di­hydro­furan ring adopts an envelope conformation with the C atom adjacent to the methyl­ene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetra­substituted) bond. In the crystal, mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming ribbons enclosing R (2) (2)(12) ring motifs lying in a plane parallel to (01-1). International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350735/ /pubmed/25844221 http://dx.doi.org/10.1107/S2056989015002017 Text en © Savithri et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Savithri, M. P.
Suresh, M.
Raghunathan, R.
Raja, R.
SubbiahPandi, A.
Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title_full Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title_fullStr Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title_full_unstemmed Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title_short Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5H)-dione
title_sort crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexa­hydro-6a,12a-(methano­epoxy­methano)­indolizino[2,3-c]quinoline-6,13(5h)-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350735/
https://www.ncbi.nlm.nih.gov/pubmed/25844221
http://dx.doi.org/10.1107/S2056989015002017
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