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Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350735/ https://www.ncbi.nlm.nih.gov/pubmed/25844221 http://dx.doi.org/10.1107/S2056989015002017 |
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author | Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. |
author_facet | Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. |
author_sort | Savithri, M. P. |
collection | PubMed |
description | In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming ribbons enclosing R (2) (2)(12) ring motifs lying in a plane parallel to (01-1). |
format | Online Article Text |
id | pubmed-4350735 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43507352015-04-03 Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(27)H(24)N(2)O(3), the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming ribbons enclosing R (2) (2)(12) ring motifs lying in a plane parallel to (01-1). International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350735/ /pubmed/25844221 http://dx.doi.org/10.1107/S2056989015002017 Text en © Savithri et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Savithri, M. P. Suresh, M. Raghunathan, R. Raja, R. SubbiahPandi, A. Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_full | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_fullStr | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_full_unstemmed | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_short | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_sort | crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5h)-dione |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350735/ https://www.ncbi.nlm.nih.gov/pubmed/25844221 http://dx.doi.org/10.1107/S2056989015002017 |
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