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Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3) O (1),O (2):O (1);3:4κ(3) O (1),O (2):O (1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2) O (1),O (2);4κ(2) O (1),O (2)-di-μ(3)-methoxido-1:2:3κ(3) O;1:3:4κ(3) O-di-μ(2)-methoxido-1:4κ(2) O;2:3κ(2) O-tetracopper(II)
The structure of the title compound, [Cu(4)(CH(3)O)(4)(C(11)H(13)O(2))(4)], consists of dimeric dinuclear copper(II) complexes oriented around a centre of inversion. Within each dinuclear fragment, the two Cu(II) atoms are in a distorted square-planar coordination sphere. Two neighbouring fragments...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350740/ https://www.ncbi.nlm.nih.gov/pubmed/25844200 http://dx.doi.org/10.1107/S205698901500376X |
| _version_ | 1782360230600900608 |
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| author | Bugenhagen, Bernhard Eberhard Christian Prosenc, Marc Heinrich |
| author_facet | Bugenhagen, Bernhard Eberhard Christian Prosenc, Marc Heinrich |
| author_sort | Bugenhagen, Bernhard Eberhard Christian |
| collection | PubMed |
| description | The structure of the title compound, [Cu(4)(CH(3)O)(4)(C(11)H(13)O(2))(4)], consists of dimeric dinuclear copper(II) complexes oriented around a centre of inversion. Within each dinuclear fragment, the two Cu(II) atoms are in a distorted square-planar coordination sphere. Two neighbouring fragments are linked by four apical Cu—O contacts, yielding an overall square-pyramidal coordination environment for each of the four Cu(II) atoms. The molecules are arranged in layers parallel to (101). Non-classical C—H⋯O hydrogen-bonding interactions are observed between the layers. |
| format | Online Article Text |
| id | pubmed-4350740 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-43507402015-04-03 Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3) O (1),O (2):O (1);3:4κ(3) O (1),O (2):O (1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2) O (1),O (2);4κ(2) O (1),O (2)-di-μ(3)-methoxido-1:2:3κ(3) O;1:3:4κ(3) O-di-μ(2)-methoxido-1:4κ(2) O;2:3κ(2) O-tetracopper(II) Bugenhagen, Bernhard Eberhard Christian Prosenc, Marc Heinrich Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title compound, [Cu(4)(CH(3)O)(4)(C(11)H(13)O(2))(4)], consists of dimeric dinuclear copper(II) complexes oriented around a centre of inversion. Within each dinuclear fragment, the two Cu(II) atoms are in a distorted square-planar coordination sphere. Two neighbouring fragments are linked by four apical Cu—O contacts, yielding an overall square-pyramidal coordination environment for each of the four Cu(II) atoms. The molecules are arranged in layers parallel to (101). Non-classical C—H⋯O hydrogen-bonding interactions are observed between the layers. International Union of Crystallography 2015-02-28 /pmc/articles/PMC4350740/ /pubmed/25844200 http://dx.doi.org/10.1107/S205698901500376X Text en © Bugenhagen and Prosenc 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Bugenhagen, Bernhard Eberhard Christian Prosenc, Marc Heinrich Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3) O (1),O (2):O (1);3:4κ(3) O (1),O (2):O (1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2) O (1),O (2);4κ(2) O (1),O (2)-di-μ(3)-methoxido-1:2:3κ(3) O;1:3:4κ(3) O-di-μ(2)-methoxido-1:4κ(2) O;2:3κ(2) O-tetracopper(II) |
| title | Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
O
(1),O
(2):O
(1);3:4κ(3)
O
(1),O
(2):O
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
O
(1),O
(2);4κ(2)
O
(1),O
(2)-di-μ(3)-methoxido-1:2:3κ(3)
O;1:3:4κ(3)
O-di-μ(2)-methoxido-1:4κ(2)
O;2:3κ(2)
O-tetracopper(II) |
| title_full | Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
O
(1),O
(2):O
(1);3:4κ(3)
O
(1),O
(2):O
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
O
(1),O
(2);4κ(2)
O
(1),O
(2)-di-μ(3)-methoxido-1:2:3κ(3)
O;1:3:4κ(3)
O-di-μ(2)-methoxido-1:4κ(2)
O;2:3κ(2)
O-tetracopper(II) |
| title_fullStr | Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
O
(1),O
(2):O
(1);3:4κ(3)
O
(1),O
(2):O
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
O
(1),O
(2);4κ(2)
O
(1),O
(2)-di-μ(3)-methoxido-1:2:3κ(3)
O;1:3:4κ(3)
O-di-μ(2)-methoxido-1:4κ(2)
O;2:3κ(2)
O-tetracopper(II) |
| title_full_unstemmed | Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
O
(1),O
(2):O
(1);3:4κ(3)
O
(1),O
(2):O
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
O
(1),O
(2);4κ(2)
O
(1),O
(2)-di-μ(3)-methoxido-1:2:3κ(3)
O;1:3:4κ(3)
O-di-μ(2)-methoxido-1:4κ(2)
O;2:3κ(2)
O-tetracopper(II) |
| title_short | Crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
O
(1),O
(2):O
(1);3:4κ(3)
O
(1),O
(2):O
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
O
(1),O
(2);4κ(2)
O
(1),O
(2)-di-μ(3)-methoxido-1:2:3κ(3)
O;1:3:4κ(3)
O-di-μ(2)-methoxido-1:4κ(2)
O;2:3κ(2)
O-tetracopper(II) |
| title_sort | crystal structure of bis(μ(2)-4-tert-butyl-2-formylphenolato)-1:2κ(3)
o
(1),o
(2):o
(1);3:4κ(3)
o
(1),o
(2):o
(1)-bis(4-tert-butyl-2-formylphenolato)-2κ(2)
o
(1),o
(2);4κ(2)
o
(1),o
(2)-di-μ(3)-methoxido-1:2:3κ(3)
o;1:3:4κ(3)
o-di-μ(2)-methoxido-1:4κ(2)
o;2:3κ(2)
o-tetracopper(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350740/ https://www.ncbi.nlm.nih.gov/pubmed/25844200 http://dx.doi.org/10.1107/S205698901500376X |
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