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Crystal structure of methyl (E)-2-(1-methyl-2-oxoindolin-3-ylidene)acetate
The title compound, C(12)H(11)NO(3), is essentially planar, with the mean plane of the acetate side chain [–C—C(=O)—O—C] being inclined to the mean plane of the indole ring system by 12.49 (7)°. The five- and six-membered rings of the indole group are almost coplanar, making a dihedral angle of 1.76...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350746/ https://www.ncbi.nlm.nih.gov/pubmed/25844241 http://dx.doi.org/10.1107/S2056989015003217 |
Sumario: | The title compound, C(12)H(11)NO(3), is essentially planar, with the mean plane of the acetate side chain [–C—C(=O)—O—C] being inclined to the mean plane of the indole ring system by 12.49 (7)°. The five- and six-membered rings of the indole group are almost coplanar, making a dihedral angle of 1.76 (8)°. The conformation about the C=C bond is E and there is an intramolecular C—H⋯O hydrogen bond present. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds forming inversion dimers, with an R (2) (2)(16) ring motif. The dimers are linked by a second pair of C—H⋯O hydrogen bonds, enclosing R (2) (2)(16) ring motifs, forming ribbons lying parallel to (-114). The ribbons are linked via C—H⋯π interactions, forming a three-dimensional structure. |
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